Alloy 27-7MO / UNS S31277 Forgings: 7% Molybdenum Super-Austenitic Stainless Steel
Key facts: Alloy 27-7MO / UNS S31277
Alloy 27-7MO (UNS S31277) is a 7% molybdenum super-austenitic stainless steel with a nominal composition of 27% nickel, 22% chromium, 7.2% molybdenum and 0.34% nitrogen, balance iron. It was developed as the next generation beyond the 6% molybdenum super-austenitic grades such as 254 SMO, AL-6XN and 25-6MO.
- PREN: approximately 51 using the common formula PREN = %Cr + 3.3 × %Mo + 16 × %N, or 43 using the Special Metals formula PREN = %Cr + 1.5 × (%Mo + %W + %Nb) + 30 × %N. Always state which formula you are quoting.
- Critical pitting temperature: greater than 85 °C in ASTM G48 Method C, above the practical ceiling of that test. Critical crevice temperature: 45 °C in ASTM G48 Method D.
- Typical room-temperature mechanical properties (annealed): 827 MPa (120 ksi) tensile strength, 414 MPa (60 ksi) 0.2% yield strength, 50% elongation, 95 HRB.
- Density: 8.02 g/cm³ (0.289 lb/in³). Non-magnetic: permeability 1.004 annealed, so magnetic particle inspection does not apply.
- Hot-working window: 980–1150 °C (1800–2100 °F). Solution anneal: 1121–1177 °C (2050–2150 °F) followed by rapid air cool or water quench. Prolonged exposure between 600 °C and 930 °C must be avoided because sigma phase forms.
- Weld filler: overmatching only. Matching-composition and autogenous welds lose corrosion resistance; use ERNiCrMo-10 (alloy 622) or ERNiCrMo-14 (686CPT-type), interpass temperature limited to 150 °C.
Who manufactures it: Jiangyin Jiangnan Metal Co., Ltd., an open-die forging factory at No.1 Chengxiqiao Road, Zhouzhuang Town, Jiangyin City, Jiangsu Province, China, produces UNS S31277 forged rings, discs, shafts, flanges, tube sheets, blocks and bars. Seamless rolled rings are made from 200 mm to 2,600 mm outside diameter and single-piece forgings up to 4,000 kg, supplied solution annealed with EN 10204 3.1 or 3.2 certification. Contact: 0086-189-2135-9659 · sales@steelforgepieces.com.
What Forged Shapes Are Available in Alloy 27-7MO / UNS S31277?
Jiangyin Jiangnan Metal Co., Ltd. manufactures UNS S31277 by three routes, selected by geometry and quantity. Seamless ring rolling is the primary route and produces rings from 200 mm to 2,600 mm outside diameter, the usual choice for scrubber shell courses, flange blanks, pressure-housing rings and pump casing rings. Open-die forging covers shafts, blocks, sleeves and large discs where the section is too heavy or too long for ring rolling. Upset forging is used for short, large-diameter discs, hubs and tube sheets.
27-7MO is harder to forge than a 300-series stainless. Its 0.34% nitrogen and 7.2% molybdenum raise the hot flow stress substantially and narrow the usable hot-working window to roughly 170 °C, so the size envelope for this grade is smaller than our general factory capacity. The figures below are the tested limits for UNS S31277 specifically.
Seamless rolled rings
200–2,600 mm OD, wall from 30 mm, height to 500 mm. Rectangular, contoured and T-section profiles. Flange blanks, shell courses, pump casing rings.
Shafts & sleeves
To 6 m length, 80–600 mm diameter. Pump and agitator shafts, scrubber spray-header spindles, hollow bored sleeves.
Discs, hubs & tube sheets
To 1,500 mm diameter, 40–350 mm thick. Heat-exchanger tube sheets, blind flanges, valve discs, cover plates.
Flanges to ASTM A182
WN, SO, BL and orifice flanges, 1/2" to 60", to ASME B16.5 and B16.47 dimensions. Class 150 to 2500.
Blocks & valve bodies
Rectangular blocks and near-net valve-body blanks to 4,000 kg single-piece weight.
Round, hollow & flat bar
30–450 mm diameter round; hollow bar with bore above 100 mm supplied trepanned to cut material input and drilling time.
What Is Alloy 27-7MO / UNS S31277 Stainless Steel?
Alloy 27-7MO (UNS S31277) is an advanced 7% molybdenum super-austenitic stainless steel that offers corrosion resistance superior to the 6% molybdenum super-austenitic grades in most environments. The name encodes the chemistry: approximately 27% nickel and 7% molybdenum. Chromium sits at about 22% and nitrogen at 0.34%, with a deliberate 0.5–1.5% copper addition and iron as the balance.
The alloy earns its performance from a balanced quartet of elements rather than from any single one. Molybdenum and chromium together with nitrogen give the resistance to pitting and crevice corrosion that defines the grade. The high nickel content plus nitrogen and molybdenum handle reducing media, while the 22% chromium handles oxidizing media, which is why 27-7MO performs unusually well in mixed acid environments where an oxidizing and a reducing acid appear together. The nickel and nitrogen also stabilize the austenite completely, so the microstructure is fully austenitic with no ferrite and the material is essentially non-magnetic.
Two consequences follow from that chemistry and matter more than any datasheet number:
- It sits in the gap between super-austenitic stainless and nickel-base alloys. In many environments its resistance approaches alloys 625, 622 and C-276 at a materially lower alloy cost, because iron is doing work that would otherwise be done by nickel. That price-to-performance position is the commercial reason the grade exists.
- It is not a drop-in replacement for 6Mo in fabrication. Like all super-austenitics it loses corrosion resistance when welded autogenously or with matching filler; it work-hardens; and its hot-working window is narrow. Getting the metallurgy right during forging and welding matters more than it does for 316L or even 904L.
Typical service is anywhere a 6Mo grade is being outrun but a nickel-base alloy is hard to justify: flue gas desulfurization scrubbers on high-sulfur coal, seawater and brine handling, chemical process equipment in mixed acids, pulp and paper bleach plants, and oil and gas components in chloride-bearing and sour environments.
How Did Alloy 27-7MO Develop? A Short Timeline
The 6% molybdenum generation arrives
254 SMO, AL-6XN and 25-6MO (UNS N08926) establish the super-austenitic class. With PREN in the low 40s they displace 316L and 904L in seawater and bleach-plant service and become the default for flue gas desulfurization.
The 6Mo ceiling becomes visible
Wet scrubbers on high-sulfur coal run at pH below 1 with high chloride and fluoride at up to 80 °C. Field corrosion rates on 6Mo alloys push operators toward nickel-base alloys such as C-276 and 622 at several times the material cost. A gap opens between the two classes.
The 7Mo composition is patented
Special Metals Corporation files the composition that becomes alloy 27-7MO, later granted as EP 1,263,999 B1. Raising molybdenum to 7.2%, chromium to 22% and nitrogen to 0.34% while holding nickel at 27% pushes PREN above the 6Mo grades without moving to a nickel-base matrix.
UNS S31277 assigned; datasheet published
The Unified Numbering System assigns S31277 to the chemistry, separating the generic alloy from the INCOLOY® brand. Special Metals publishes technical bulletin SMC-092 in December 2005 with the composition limits, mechanical data and corrosion results still cited today.
Written into ASTM and ASME
S31277 is listed in ASTM A240 (plate, sheet, strip), A479 (bar and forging stock), A213/A249 (tube), A312 (pipe) and A182 (forged flanges, fittings and valves). ASME Code Case 2458 establishes allowable design stresses for pressure-vessel construction.
Oil and gas adoption
U-bend specimens survive two months in boiling saturated sodium chloride without stress-corrosion cracking or pitting. The alloy is taken up for wireline, armor wire, sand screens and subsea banding, where its combination of strength and chloride resistance is hard to match.
Generic supply and forged products
With the composition patent at the end of its standard term and the UNS designation firmly generic, independent forging producers, including Jiangyin Jiangnan Metal Co., Ltd., supply UNS S31277 rings, discs, shafts and flanges against ASTM and ASME specifications, widening availability beyond mill product forms.
What Designations and Specifications Cover UNS S31277?
Unlike older stainless grades, 27-7MO has a short and clean designation list. There is no AISI number, no widely used EN 10088-3 designation and no JIS equivalent. The alloy postdates those numbering systems. In practice every purchase order should carry UNS S31277 plus the ASTM or ASME product specification appropriate to the form.
| Body / region | Designation | Applies to | Notes |
|---|---|---|---|
| USA · UNS | UNS S31277 | All forms | The generic designation. Use this on every drawing and PO. |
| USA · Brand | INCOLOY® alloy 27-7MO | - | Registered trademark of Special Metals Corporation. Material sold under this name is theirs; we supply the generic UNS S31277 equivalent. |
| ASTM / ASME | ASTM A479 / SA-479 | Bar, rod, wire, forging stock | The usual governing spec for forged bar and billet input. |
| ASTM / ASME | ASTM A182 / SA-182 | Forged flanges, fittings, valves and parts | The governing spec for most finished forgings on pressure systems. |
| ASTM / ASME | ASTM A240 / SA-240 | Plate, sheet, strip | Chemistry reference frequently cited even when ordering forgings. |
| ASTM / ASME | ASTM A312 / SA-312 | Welded and seamless pipe | For piping tied to forged flanges on the same system. |
| ASTM / ASME | ASTM A213 · A249 / SA-213 · SA-249 | Seamless and welded tube | Heat-exchanger and boiler tube; pairs with S31277 tube sheets. |
| ASME BPVC | Code Case 2458 | Allowable design stresses | Required reference for ASME Section VIII pressure-vessel design in this alloy. |
| Europe · EN | No EN 10088-3 number assigned | - | European projects specify UNS S31277 per ASTM/ASME directly. Add PED 2014/68/EU particular material appraisal where required. |
| Japan · JIS | No JIS equivalent | - | Japanese purchasers specify UNS S31277 per ASTM. |
| Oil & gas | NACE MR0175 / ISO 15156-3 | Sour service qualification | Applied on top of the base specification. Confirm the current annex listing and any hardness or environmental limits for your service envelope. |
Designation & Specification Lookup
Type any name, number or specification (27-7MO, S31277, A182, A479, "7 Mo", scrubber alloy) and see what it maps to.
All ASTM and ASME references are to the specification family; always cite the revision in force at your contract date. Jiangyin Jiangnan Metal Co., Ltd. issues material test certificates listing UNS S31277 plus every equivalent product specification the heat also satisfies.
What Is the Chemical Composition of Alloy 27-7MO / UNS S31277?
The limiting chemical composition below is the published UNS S31277 specification. Note the two unusual features: nitrogen carries a minimum of 0.30%, which is what lifts the PREN so far above a 6Mo grade, and copper is deliberately added at 0.5–1.5% to improve resistance in reducing acids, particularly sulfuric. Carbon is held to 0.020% maximum to keep chromium carbide precipitation out of the heat-affected zone.
| Element | Min | Max | Typical | Metallurgical role |
|---|---|---|---|---|
| Nickel (Ni) | 26.0 | 28.0 | 27.0 | Stabilizes austenite fully; resistance to reducing media, caustics and chloride stress-corrosion cracking |
| Chromium (Cr) | 20.5 | 23.0 | 22.0 | Passive film; resistance to oxidizing media; largest single term in PREN |
| Molybdenum (Mo) | 6.5 | 8.0 | 7.2 | Pitting and crevice resistance; resistance to reducing acids. The defining addition of the grade |
| Nitrogen (N) | 0.30 | 0.40 | 0.34 | Austenite stabilizer, solid-solution strengthener, and the most potent element in PREN per unit weight |
| Copper (Cu) | 0.5 | 1.5 | 1.0 | Deliberate addition improving resistance in sulfuric and other reducing acids |
| Iron (Fe) | Balance | ~43 | Matrix. Keeping iron as the matrix rather than nickel is the alloy's cost advantage | |
| Manganese (Mn) | - | 3.00 | - | Deoxidizer; increases nitrogen solubility during melting |
| Silicon (Si) | - | 0.5 | - | Deoxidizer; capped low to limit sigma-phase formation |
| Carbon (C) | - | 0.020 | - | Held very low to prevent chromium-carbide sensitization at grain boundaries |
| Phosphorus (P) | - | 0.03 | - | Residual; hot-shortness control |
| Sulfur (S) | - | 0.01 | - | Residual; low sulfur reduces manganese-sulfide pit initiation sites |
What Are the Mechanical Properties of Alloy 27-7MO?
UNS S31277 is supplied and used in the solution-annealed condition. It is not precipitation hardened and there is no aging cycle, a point that trips up engineers coming from 17-4PH or A286. Strength comes from nitrogen in solid solution, which is why the yield strength is roughly double that of 316L while ductility stays at 50% elongation.
| Alloy | UTS | Yield (0.2%) | Elongation | Hardness |
|---|---|---|---|---|
| Alloy 27-7MO (UNS S31277) | 827 MPa / 120 ksi | 414 MPa / 60 ksi | 50% | 95 HRB |
| 25-6MO (UNS N08926, 6Mo) | 655 MPa / 95 ksi | 310 MPa / 45 ksi | 42% | 90 HRB |
| Alloy 625 (UNS N06625) | 862 MPa / 125 ksi | 469 MPa / 68 ksi | 50% | 95 HRB |
| Alloy C-276 (UNS N10276) | 724 MPa / 105 ksi | 345 MPa / 50 ksi | 60% | 88 HRB |
The practical reading of that table: 27-7MO carries about 33% more yield strength than a 6Mo grade and sits within a few percent of alloy 625. On a pressure-retaining part designed by allowable stress, that difference translates directly into thinner walls, often enough to offset the alloy premium over 6Mo on the finished component. For ASME Section VIII design, allowable stresses come from Code Case 2458, not from the typical values above.
The alloy work-hardens at a rate similar to 25-6MO, meaningfully faster than carbon steel or 304, and this governs both machining and cold forming. Cold work raises hardness steeply; heavily cold-drawn wire reaches well above 400 HV, which is why the grade found a niche in oilfield armor wire.
What Are the Physical and Thermal Properties of UNS S31277?
| Property | Value (metric) | Value (imperial) | Condition / note |
|---|---|---|---|
| Density | 8.02 g/cm³ | 0.289 lb/in³ | Room temperature. Use this for forging weight calculations |
| Young's modulus | 191 GPa | 27.7 × 10³ ksi | 22 °C; falls to 138 GPa at 816 °C |
| Shear modulus | 74 GPa | 10.8 × 10³ ksi | 22 °C |
| Poisson's ratio | 0.29 | 0.29 | 22 °C |
| Specific heat | 454 J/kg·°C | 0.109 Btu/lb·°F | Room temperature |
| Electrical resistivity | 100 µΩ·cm | 604 Ω·circ mil/ft | Room temperature, high, so plan for slow induction heating |
| Coefficient of thermal expansion | 15.0 × 10⁻⁶ /°C | 8.33 × 10⁻⁶ /°F | Approximately 20–100 °C; rises to 16.6 × 10⁻⁶ /°C at 300 °C |
| Magnetic permeability | 1.004 | 1.004 | Annealed, at 200 oersted. Below 1.01 even after 50% cold work |
| Magnetic response | Non-magnetic (fully austenitic) | Magnetic particle inspection is not applicable. Specify liquid penetrant instead | |
How Corrosion-Resistant Is Alloy 27-7MO? PREN, CPT and CCT
Pitting Resistance Equivalent Number, and Why the Formula Matters
PREN ranks alloys by their resistance to localized chloride attack. The trap is that at least two PREN formulas are in common use and they give very different numbers for the same alloy. Comparing a value from one formula against a value from the other is meaningless, and it happens constantly in supplier literature.
| Alloy | %Cr | %Mo | %W | %Nb | %N | PREN₁₆ Cr+3.3Mo+16N | PREN (SMC) Cr+1.5(Mo+W+Nb)+30N |
|---|---|---|---|---|---|---|---|
| Alloy 27-7MO (S31277) | 22 | 7.2 | 0 | 0 | 0.34 | 51.2 | 43.0 |
| Alloy C-276 (N10276) | 16 | 16 | 3.5 | 0 | 0 | 68.8 | 45.2 |
| AL-6XN (N08367, 6Mo) | 21 | 6.3 | 0 | 0 | 0.22 | 45.3 | 37.0 |
| 254 SMO (S31254, 6Mo) | 20 | 6.1 | 0 | 0 | 0.20 | 43.3 | 35.2 |
| 2507 super duplex (S32750) | 25 | 3.8 | 0 | 0 | 0.28 | 42.0 | 39.1 |
| Alloy 625 (N06625) | 22 | 9 | 0 | 3.5 | 0 | 51.7 | 40.8 |
| 25-6MO (N08926, 6Mo) | 20 | 6.5 | 0 | 0 | 0.20 | 44.6 | 35.8 |
| 904L (N08904) | 20 | 4.3 | 0 | 0 | 0.05 | 35.0 | 28.0 |
| 2205 duplex (S32205) | 22 | 3.2 | 0 | 0 | 0.17 | 35.3 | 32.0 |
| 316L (S31603) | 17 | 2.2 | 0 | 0 | 0.05 | 25.1 | 21.8 |
Read the two right-hand columns separately. Under PREN₁₆, the formula most widely used for stainless steels and the one behind the familiar "PREN 40 for seawater" rule of thumb, 27-7MO reaches about 51, comfortably ahead of every 6Mo grade and every duplex. Under the Special Metals formula, which weights tungsten and niobium and is intended for cross-comparison with nickel-base alloys, 27-7MO scores 43 against 45.2 for C-276 and 40.8 for alloy 625. Either way the ranking of 27-7MO against the 6Mo grades is the same, and that ranking is the commercially relevant one.
Critical pitting and crevice temperatures (ASTM G48)
PREN is a calculation. CPT and CCT are measurements, and they are the numbers to put in a specification. In ASTM G48 the test solution becomes unstable above 85 °C, so ">85 °C" is a ceiling of the method rather than a property of the alloy.
| Alloy | CPT (Method C) | CCT (Method D) |
|---|---|---|
| Alloy 27-7MO (S31277) | >85 °C (>185 °F) | 45 °C (113 °F) |
| Alloy C-276 | >85 °C (>185 °F) | 50 °C (122 °F) |
| Alloy 625 | >85 °C (>185 °F) | 35 °C (95 °F) |
| UNS N08031 (Alloy 31) | 75 °C (167 °F) | 45 °C (113 °F) |
| 25-6MO (N08926, 6Mo) | 70 °C (158 °F) | 35 °C (95 °F) |
The line worth noticing is the comparison with alloy 625: 27-7MO matches 625 on pitting and beats it on crevice corrosion (45 °C against 35 °C) at a substantially lower alloy cost. Crevice corrosion, not pitting, is what usually kills flanged and gasketed equipment, so that ten-degree margin is more valuable in the field than the headline PREN suggests.
In the more aggressive "green death" solution (11.9% H₂SO₄ + 1.3% HCl + 1% FeCl₃ + 1% CuCl₂), 27-7MO records a CPT of 75 °C and a CCT of 60 °C, against 60 °C and 45 °C for 25-6MO and 75 °C and 55 °C for alloy 625. Tested to ASTM G28 Method A, annealed wrought 27-7MO shows a typical corrosion rate of 15 mpy (0.38 mm/a).
PREN Calculator for Your Actual Heat Analysis
Enter the chemistry from your material test certificate and get PREN by both formulas, plus where your specific heat ranks against ten reference grades.
PREN is a screening index, not a design value. It does not account for surface finish, weld metal dilution, heat tint, crevice geometry, flow velocity, biofilm, or the presence of oxidizing species such as free chlorine, all of which can dominate real service. Confirm marginal cases with ASTM G48 testing on the actual heat and, where practical, on a welded coupon. Jiangyin Jiangnan Metal Co., Ltd. can supply G48 Method C or D test results with the material test certificate on request.
Chloride Service Suitability Check
Describe the environment (chloride, temperature, pH, whether crevices are present) and get a first-pass verdict on whether UNS S31277 is the right choice or an upgrade is needed.
Screening tool only, based on published ASTM G48 critical temperatures and general chloride-service practice. It does not replace corrosion testing, a materials engineer's review, or the requirements of the governing design code. Real systems fail at crevices, under deposits and at weld heat tint far more often than on clean parent metal.
How Does Alloy 27-7MO Perform in Acids and FGD Scrubbers?
Mixed-acid performance is where 27-7MO separates itself from the 6Mo grades most clearly. Molybdenum handles the reducing acids, chromium handles the oxidizing acids, and the copper addition helps in sulfuric, so the alloy does not have the "good in one, poor in the other" behaviour that forces material changes partway along a process line.
| Test medium | Temp | 25-6MO (6Mo) | 27-7MO | Alloy 625 | Alloy C-276 |
|---|---|---|---|---|---|
| 0.5% HCl | Boiling | - | 0.2 (0.005) | 0.7 (0.018) | 0.8 (0.020) |
| 1% HCl | Boiling | 218 (5.54) | 15 (0.38) | 1.3 (0.033) | 6.5 (0.165) |
| 5% HCl | 50 °C | 45 (1.14) | <0.1 (<0.0025) | <0.1 (<0.0025) | 0.5 (0.013) |
| 10% H₂SO₄ | 90 °C | 33 (0.84) | 1.5 (0.04) | 1 (0.025) | <0.1 (<0.0025) |
| 95% H₂SO₄ | 50 °C | 18 (0.46) | 48 (1.22) | 14 (0.36) | 0.1 (0.0025) |
| 10% H₂SO₄ + 2% HCl | 50 °C | 29 (0.74) | <0.1 (<0.0025) | <0.1 (<0.0025) | <0.1 (<0.0025) |
| 10% H₂SO₄ + 1,000 ppm Cl⁻ | 65 °C | 26 (0.66) | 0 (0) | - | 1 (0.025) |
| 10% H₂SO₄ + 10,000 ppm Cl⁻ | 65 °C | 26 (0.66) | <0.5 (<0.01) | - | 0.5 (0.01) |
| 85% H₃PO₄ | Boiling | 30 (0.76) | 27 (0.69) | 180 (4.57) | 13 (0.33) |
Three readings stand out. In chloride-contaminated dilute sulfuric acid: the exact chemistry of a wet scrubber liquor, 27-7MO is essentially unattacked while a 6Mo grade corrodes at 26 mpy: a factor of fifty or more. In boiling 85% phosphoric acid it outperforms alloy 625 by nearly seven to one, which is why it appears in fertilizer and phosphoric-acid plants. But in concentrated 95% sulfuric acid it is worse than 25-6MO and far worse than C-276, concentrated sulfuric is the one place this alloy should not be assumed adequate.
Simulated flue gas desulfurization environment
Wet scrubbers on high-sulfur coal are the application the alloy was designed around. The environment inside the absorber is typically sulfuric acid at pH 1 or below, carrying significant chloride and fluoride, at temperatures up to 80 °C. Testing in a standard FGD ranking solution (60% H₂SO₄ + 2.5% HCl + 0.2% HF + 0.5% flyash at 80 °C for one week) produced these rates:
| Alloy | Corrosion rate | Position |
|---|---|---|
| 25-6MO (6Mo super-austenitic) | 199 (5.08) | Baseline 6Mo |
| UNS N08031 | 177 (4.50) | High-alloy austenitic |
| Alloy 27-7MO (S31277) | 153 (3.91) | Roughly 23% better than 6Mo at a fraction of the nickel-alloy cost |
| UNS N06059 (Ni-Cr-Mo) | 47 (1.20) | Nickel-base |
| Alloy 622 | 40 (1.02) | Nickel-base |
| Alloy C-276 | 28 (0.71) | Nickel-base |
| Alloy 686 | 23 (0.58) | Nickel-base |
How Does Alloy 27-7MO Behave in Seawater and Sour Service?
Seawater
In a crevice-corrosion programme run at the LaQue Center for Corrosion Technology in Wrightsville Beach, North Carolina, sheet specimens with PTFE crevice devices attached were exposed to flowing natural seawater at 30 °C for 60 days:
| Alloy | PREN of test material | Max area attacked (mm²) | Max depth of attack (mm) |
|---|---|---|---|
| 316L stainless steel | 21.2 | 1,745 | 2.84 |
| 6% Mo super-austenitic | 37.0 | 80 | 0.01 |
| Alloy 625 | 40.2 | 0 | 0 |
| Alloy 27-7MO (S31277) | 41.6 | 0 | 0 |
| Alloy C-276 | 45.2 | 1 | 0.02 |
Zero measurable crevice attack under a deliberately severe artificial crevice, in real flowing seawater, over two months, matching alloy 625 and marginally better than C-276 in this particular test. For seawater cooling, desalination, offshore firewater and ballast systems this is the headline result. The alloy also resists chloride stress-corrosion cracking in sodium chloride at all concentrations up to saturation at the boiling point, a claim 316L and 904L cannot make.
Sour service (H₂S)
U-bend specimens of 27-7MO exposed for two months in boiling saturated sodium chloride showed no stress-corrosion cracking and no pitting. In armor-wire qualification testing on cold-worked 0.031 in wire, samples stressed by wrapping the wire upon itself survived a battery of sour and chloride tests without cracking, and were not attacked in the G48-D crevice test at 25 °C. Established oilfield applications include wireline, armor wire, sand screens and subsea banding.
When Should You Choose 27-7MO Over 6Mo, 904L, Super Duplex or a Nickel Alloy?
| Property | 27-7MO S31277 | 254 SMO / AL-6XN 6Mo | 904L N08904 | 2507 super duplex | Alloy 625 N06625 | C-276 N10276 |
|---|---|---|---|---|---|---|
| Structure | Austenitic | Austenitic | Austenitic | Duplex | Ni-base | Ni-base |
| Nickel content | ~27% | 18–24% | ~25% | ~7% | ~62% | ~58% |
| PREN₁₆ | ~51 | 43–45 | ~35 | ~42 | ~52 | ~69 |
| CPT (G48-C) | >85 °C | 70–80 °C | ~40 °C | ~75 °C | >85 °C | >85 °C |
| Yield strength | 414 MPa | ~310 MPa | ~220 MPa | ~550 MPa | ~469 MPa | ~345 MPa |
| Chloride SCC | Resistant to saturated NaCl at boiling | Good | Moderate | Good, but limited above 300 °C | Excellent | Excellent |
| Max service temp | ~600 °C* | ~600 °C* | ~400 °C | ~300 °C | ~980 °C | ~1,040 °C |
| Magnetic | No | No | No | Yes | No | No |
| Relative alloy cost | ~2.5× | ~2× | ~1.6× | ~1.5× | ~5× | ~6× |
| Choose it when… | 6Mo is marginal but a nickel alloy is unaffordable; mixed acids; high-chloride with crevices | Proven 6Mo duty; cost-driven seawater service | Sulfuric acid service without high chloride | Strength-driven, chloride present, temperature below 300 °C | High temperature plus corrosion; weld overlay | The most aggressive reducing acids and hot HCl |
* Austenitic grades retain strength above these temperatures, but prolonged exposure in the 600–930 °C range precipitates sigma phase in 27-7MO and embrittles it. The figure quoted is a practical continuous-service ceiling for corrosion service, not a scaling or creep limit.
27-7MO is the right choice when:
- An existing 6Mo component is corroding faster than its design life allows, particularly at crevices and gaskets
- The process contains both oxidizing and reducing acids, or the chemistry shifts along the line
- Chloride is present at high concentration with elevated temperature and the geometry is inherently crevice-prone
- A nickel-base alloy has been specified out of caution but the cost is blocking the project
- Higher yield strength would allow a thinner section and offset the alloy premium
Look elsewhere when:
- The medium is concentrated sulfuric acid above about 90%, 27-7MO is outperformed even by 6Mo there
- Service is continuously in the 600–930 °C range, sigma phase will embrittle the part
- The duty is hot concentrated hydrochloric acid, C-276 or 686 territory
- Existing 6Mo has a proven service record in the same duty and there is no corrosion problem to solve
- The part is small, thin and welded throughout, where the overmatching filler cost and weld procedure burden outweigh the parent-metal gain
Grade Substitution Finder: Should You Move to 27-7MO?
Pick what you are using today and what is driving the change. Get a direct verdict on whether UNS S31277 is the right move, what improves and what you have to watch.
Comparison uses published typical properties for each grade. A material change on an in-service asset should be reviewed by a corrosion or materials engineer against the actual process envelope, the applicable design code, and any galvanic coupling with existing components.
How Is Alloy 27-7MO Forged and Heat Treated?
This is the section that decides whether a UNS S31277 forging is sound or scrap. Three parameters govern everything.
Hot-working window: 980–1150 °C
Only about 170 °C of usable range against roughly 400 °C for carbon steel. Below 980 °C the alloy work-hardens hard and cracks; above 1150 °C incipient melting and grain coarsening set in. Frequent reheats are mandatory on heavy sections.
Solution anneal: 1121–1177 °C
Followed by rapid air cool or water quench. This is the delivery condition. There is no aging step, 27-7MO is not a precipitation-hardening alloy.
Forbidden zone: 600–930 °C
Prolonged exposure precipitates sigma phase and can sensitize the alloy, causing intergranular attack and increased stress-corrosion cracking susceptibility. The quench after annealing exists to race through this band.
Catastrophic oxidation, the failure mode nobody warns you about
Our production sequence for UNS S31277 forgings
- Raw material. Billet or bar to the ASTM A479 chemistry, heat-number traced, chemistry verified by optical emission spectrometry on receipt. High-cleanliness routes (ESR, or VIM + ESR + VAR for critical work) are used where the project requires them.
- Preheat and soak. Slow, uniform heating to 1150 °C. Because electrical resistivity is high and thermal conductivity low, heavy sections need generous soak time, a thermal gradient during the first blow is a common cause of centre bursts.
- Forging. Reduction in the 980–1150 °C window, forging ratio 4:1 or better to break down the cast structure. Multi-step incremental reduction with reheats whenever surface temperature approaches 1000 °C.
- Ring rolling (where applicable). Radial–axial rolling to final ring geometry, finishing above 980 °C.
- Solution anneal. 1121–1177 °C, hold approximately 30 minutes per 25 mm of section, then rapid water quench. On thin rings a forced air quench is acceptable; on anything above roughly 60 mm section, water.
- Pickling and passivation. Descale and remove heat tint. Heat tint left on a surface measurably reduces local pitting resistance, so this step is functional, not cosmetic.
- Machining. Rough or finish machining to drawing.
- NDT and testing. Ultrasonic examination to ASTM A388, liquid penetrant to ASTM E165, tensile and hardness testing, plus ASTM G48 or A262 corrosion testing when specified. Magnetic particle testing is not applicable. The alloy is non-magnetic.
- Certification and dispatch. EN 10204 3.1 as standard, or 3.2 with a nominated third-party witness. Marking with heat number, specification and drawing number.
Forging & Solution-Anneal Recipe Generator
Enter the shape and section thickness and get a complete, printable cycle you can hand to a forge shop or heat-treatment vendor.
Cycles follow the published hot-working and annealing windows for UNS S31277. Soak times scale at roughly 30 minutes per 25 mm of section above 25 mm. Furnace uniformity should be held to ±10 °C or better and the atmosphere kept moving. See the catastrophic-oxidation warning above. Always confirm final properties on test coupons taken from the same heat and heat-treatment charge.
Sigma-Phase & Sensitization Risk Check
How long will your part spend between 600 °C and 930 °C? Enter the cooling situation and get a risk verdict before you commit a heat-treatment charge.
Estimates cooling time through the 600–930 °C precipitation band from section thickness and quench severity using standard Grossmann-type severity factors. Indicative only; actual cooling depends on part geometry, surface condition, quench tank agitation, load density and rack design. Where sigma phase is a project risk, require a metallographic check to ASTM E562 or an ASTM A262 Practice E intergranular corrosion test on the delivered heat-treatment lot.
How Do You Weld Alloy 27-7MO / UNS S31277?
UNS S31277 welds readily by GTAW, GMAW, SMAW, SAW and PAW using conventional equipment. There is one rule that overrides everything else, and getting it wrong is the single most common cause of premature failure in super-austenitic equipment.
Procedure essentials
- Filler: ERNiCrMo-10 (622) standard; ERNiCrMo-14 (686CPT) for severe service
- Interpass temperature: limit to 150 °C (300 °F)
- Heat input: keep low, minimizes elemental segregation in the fusion zone
- Dilution: minimize. Low-dilution procedures give the most corrosion-resistant weldments
- Preheat: not required. Preheating an austenitic alloy adds time in the sensitization range for no benefit
- PWHT: not required when overmatching filler is used
After welding
- Autogenous welds (if unavoidable) must be post-weld heat treated at 1100 °C minimum for at least 5 minutes, then air cooled or water quenched
- That same treatment also improves corrosion resistance of filler-metal welds
- Pickle after welding or heat treatment: generally effective in restoring corrosion resistance
- Remove heat tint, including on the back side of the joint. Back-face heat tint is a frequent and avoidable cause of service pitting
- Purge with argon on the root side of full-penetration welds
Weld Filler & Procedure Selector
Tell us the joint and the service, and get the correct overmatching filler, process, interpass limit and post-weld requirement.
Recommendations reflect published guidance for 7% Mo super-austenitic stainless steels. Every production weld must still be qualified to the governing code (ASME Section IX, ISO 15614 or equivalent) with corrosion testing on the qualification coupon where the service demands it.
How Do You Machine Alloy 27-7MO?
Machining characteristics are similar to other austenitic alloys, and the alloy is machined in the annealed condition. Three behaviours drive the parameters: it work-hardens quickly, it has low thermal conductivity so heat stays in the cutting zone rather than leaving in the chip, and it produces tough, stringy chips.
- Never dwell or rub. A tool that stops feeding while still in contact glazes the surface into a work-hardened layer the next pass cannot cut. Maintain positive, continuous feed and withdraw under power.
- Take deep enough cuts to get under the previous pass's hardened layer. Light spring passes are the classic way to ruin a super-austenitic part.
- Flood coolant, generously. Low thermal conductivity means the tool tip carries the heat.
- Rigid setups, sharp positive-rake carbide. Chatter accelerates work hardening and tool failure.
- Peck-drill deep holes and clear chips aggressively to prevent packing and re-cutting.
Machining Parameter Calculator for UNS S31277
Choose the operation and tooling and get starting cutting speed, feed, depth of cut and expected tool life.
Starting values for solution-annealed UNS S31277. Final selection depends on machine rigidity, setup stiffness, tool holder geometry and required surface finish. This alloy work-hardens: never dwell, keep the feed positive, and take a depth of cut greater than the previous pass's hardened layer. Flood coolant strongly recommended for all operations.
Production Capability, UNS S31277 Forging Manufacturer
Jiangyin Jiangnan Metal Co., Ltd. is an open-die forging factory located at No.1 Chengxiqiao Road, Zhouzhuang Town, Jiangyin City, Jiangsu Province, China. The company employs approximately 460 people, including 9 senior engineers and 32 intermediate engineers, and has been producing open-die forgings and seamless rolled rings since 2008 for customers in more than 40 countries.
Forging equipment
- Open-die forging hammers: 1 t, 3 t, 5 t and 9 t
- Hydraulic press: 5,000 t
- Radial–axial ring rolling mills: 3 m and 6 m
- Melting routes available for input stock: ESR, and VIM + ESR + VAR for critical work
Testing and inspection
- Optical emission spectrometer, full elemental analysis
- Universal testing machine, tensile to ASTM E8
- Impact testing machine, Charpy V to ASTM E23
- Hardness testing, HRB / HB / HV
- Ultrasonic flaw detection to ASTM A388
- Metallographic microscope, grain size to ASTM E112
- Liquid penetrant to ASTM E165 (magnetic particle not applicable, S31277 is non-magnetic)
UNS S31277 size envelope
| Product form | Size range | Max weight | Typical use |
|---|---|---|---|
| Seamless rolled rings | 200–2,600 mm OD · wall from 30 mm · height to 500 mm | 3,000 kg | Absorber shell courses, flange blanks, pump casing rings |
| Forged discs & tube sheets | To 1,500 mm Ø · 40–350 mm thick | 4,000 kg | Heat-exchanger tube sheets, blind flanges, covers |
| Forged shafts & sleeves | 80–600 mm Ø · to 6,000 mm long | 2,500 kg | Pump and agitator shafts, spray-header spindles |
| Forged blocks & valve bodies | To 1,200 × 800 × 600 mm | 4,000 kg | Valve bodies, manifold blocks, near-net blanks |
| Round & hollow bar | 30–450 mm Ø · to 6,000 mm long | - | Machining stock, trepanned hollow bar for bored parts |
| Flanges to ASTM A182 | 1/2" to 60", Class 150–2500 | - | WN, SO, BL and orifice flanges to ASME B16.5 / B16.47 |
Where a project needs sizes beyond this envelope, our general factory capability extends to 6,000 mm ring diameter, 12,000 mm length and 15,000 kg single-piece weight in more readily forged grades. Send the drawing and we will confirm feasibility in UNS S31277 specifically.
UNS S31277 Forging Weight Calculator
Pick a shape, enter dimensions, and get finished weight at 8.02 g/cm³ plus an estimated rough forging weight for your enquiry.
Uses UNS S31277 density 8.02 g/cm³ (0.289 lb/in³). The result is net finished weight; the rough forging weight shown adds a typical machining allowance of 20–35% depending on geometry and tolerance. Maximum single-piece capability for this grade at Jiangyin Jiangnan Metal Co., Ltd. is 4,000 kg.
Which Standards and Quality Documents Apply?
Material & product specifications
- ASTM A479 / ASME SA-479: bar, rod, wire and forging stock
- ASTM A182 / ASME SA-182: forged flanges, fittings, valves and parts
- ASTM A240 / ASME SA-240: plate, sheet and strip
- ASTM A312 / A213 / A249, pipe and tube
- ASME Code Case 2458: allowable design stresses for BPVC construction
- ASME B16.5 / B16.47, flange dimensions
- NACE MR0175 / ISO 15156-3, sour service, confirm per project
Testing & certification
- ASTM E8: tensile testing
- ASTM E23: Charpy V-notch impact
- ASTM E112: grain size
- ASTM G48 Method C / D: critical pitting and crevice temperature
- ASTM A262 / ASTM G28: intergranular corrosion
- ASTM A388: ultrasonic examination of forgings
- ASTM E165: liquid penetrant
- EN 10204 3.1 standard; 3.2 with third-party witness on request
- ISO 9001:2015 quality management system
Quality gates and non-conformance handling
Every UNS S31277 order passes six mandatory hold points at which production cannot continue without quality sign-off: incoming chemistry verification, forging temperature compliance, post-forging ultrasonic examination, heat-treatment chart approval, mechanical and corrosion test acceptance, and final NDE plus dimensional inspection. Customer-witnessed hold points can be added at no charge. Any out-of-specification finding raises a formal non-conformance report within 24 hours, with root-cause analysis completed within five working days and the proposed disposition sent to the customer before any action is taken. Shipping and test documentation is retained for ten years.
How Do You Specify an Alloy 27-7MO Forging Order?
- State the generic designation. Write UNS S31277 plus the governing product specification, ASTM A182 for flanges and fittings, ASTM A479 for bar and forging stock, ASTM A240 where plate chemistry is the reference. Do not order under a trademarked brand name.
- Define the forged shape and envelope. Outside diameter, inside diameter, height or length, wall thickness, finished weight, and machining allowance if the part is supplied rough machined.
- Specify the delivery condition. "Solution annealed at 1121–1177 °C, rapid water quench." There is no aging or hardening condition to choose. If a supplier offers you one, they have confused this grade with a precipitation-hardening alloy.
- Specify corrosion testing where it matters. ASTM G48 Method C or D with a stated acceptance temperature for chloride service; ASTM A262 Practice E or ASTM G28 Method A for intergranular attack. Consider adding a minimum PREN clause, since the specification band spans roughly nine PREN points.
- Specify NDT correctly. Ultrasonic to ASTM A388 with the acceptance class, liquid penetrant to ASTM E165. Do not specify magnetic particle inspection: the alloy is non-magnetic and the requirement cannot be met.
- Specify certification. EN 10204 3.1 as standard, or 3.2 with a nominated third-party witness (DNV, BV, Lloyd's Register, ABS, TÜV). Add NACE MR0175 / ISO 15156 compliance and your full H₂S, chloride, pH and temperature envelope if the service is sour.
- Give quantity, date and destination. Piece count, required delivery date, port and Incoterm. Typical lead time is 8–12 weeks; add 2–4 weeks for third-party witnessed release.
Top 10 Mistakes When Specifying Alloy 27-7MO Forgings
- Quoting a PREN without saying which formula. The same heat is "PREN 51" or "PREN 43" depending on the equation. Purchasing teams compare across suppliers and reach the wrong conclusion. Fix: write the formula next to the number on every document.
- Ordering the grade name and nothing else. A heat at the bottom of the composition band computes to PREN ≈ 47; one at the top reaches ≈ 56. Fix: state a minimum PREN, or minimum Mo and N, on the purchase order for critical chloride service.
- Specifying magnetic particle inspection. UNS S31277 is fully austenitic and non-magnetic; MPI cannot be performed. Fix: specify liquid penetrant to ASTM E165.
- Asking for an age-hardened or "H-condition" delivery state. This is not a precipitation-hardening alloy. Fix: specify solution annealed and quenched.
- Allowing matching or autogenous welds. Molybdenum segregation makes a matching-composition weld the weakest corrosion link in the assembly. Fix: mandate ERNiCrMo-10 or ERNiCrMo-14 overmatching filler in the weld procedure specification.
- Leaving heat tint on the back of welds. Back-face heat tint is invisible from the inspection side and is a routine cause of premature pitting. Fix: require argon purging plus mechanical or chemical removal of heat tint on both faces.
- Stacking parts in the annealing furnace. Stagnant oxidizing conditions above 925 °C cause catastrophic oxidation at the contact faces. Fix: require spacers and forced atmosphere circulation in the heat-treatment procedure.
- Slow cooling from the solution anneal. Time between 600 °C and 930 °C precipitates sigma phase and sensitizes the alloy. Fix: require rapid water quench on heavy sections and verify with a heat-treatment chart, not a verbal assurance.
- Assuming it replaces C-276 everywhere. In concentrated sulfuric acid, and in the most severe FGD zones, it does not. Fix: match the alloy to the zone rather than the plant.
- Treating published sour-service test data as a NACE compliance statement. Qualification depends on the annex listing and your specific environmental envelope. Fix: require the qualification route in writing before ordering.
Drawing Callout Template for UNS S31277 Forgings
Copy this into your material callout box
MATERIAL: UNS S31277 super-austenitic stainless steel
per ASTM A182 (forged flanges/fittings)
[or ASTM A479 for bar and forging stock]
CHEMISTRY: Ni 26.0-28.0 / Cr 20.5-23.0 / Mo 6.5-8.0
N 0.30-0.40 / Cu 0.5-1.5 / C 0.020 max
MINIMUM PREN 50 (PREN = %Cr + 3.3x%Mo + 16x%N)
CONDITION: Solution annealed 1121-1177 C, rapid water quench
No aging or precipitation-hardening treatment
FORGING: Hot work 980-1150 C only. Forging ratio >= 4:1.
Forced atmosphere circulation in furnace; do not stack.
CORROSION: ASTM G48 Method C, CPT >= 65 C, no pitting
ASTM A262 Practice E - pass, no fissures
[state acceptance temperature for your service]
NDE: UT per ASTM A388, acceptance class [state class]
PT per ASTM E165 Type I Method C
MT NOT APPLICABLE - material is non-magnetic
WELDING: Overmatching filler only - ERNiCrMo-10 (622)
or ERNiCrMo-14. Interpass max 150 C.
Matching or autogenous welds NOT permitted.
Argon purge root side; remove all heat tint.
SURFACE: Pickled and passivated. No heat tint permitted
on any wetted surface.
CERTIFICATE: EN 10204 3.1 [or 3.2 with witness by ______ ]
MARKING: Heat number, UNS S31277, specification,
drawing number - low-stress stamp or vibro-etch
RFQ Generator for UNS S31277
Fill the fields and get a complete, professional enquiry text ready to paste into an email or send by WhatsApp.
Nothing is submitted from this page. The text is generated in your browser for you to send yourself. Jiangyin Jiangnan Metal Co., Ltd. replies to technical enquiries within 24 hours.
Where Is Alloy 27-7MO / UNS S31277 Used?
Flue gas desulfurization
Absorber shell courses, spray-header supports and spindles, outlet ducting, recirculation pump casings and agitator shafts in wet limestone scrubbers on high-sulfur coal. The moderate-severity zones where 6Mo has proven marginal.
Seawater and desalination
Seawater cooling, ballast and firewater systems, MSF and RO desalination components, offshore piping flanges. Zero crevice attack in 60-day flowing-seawater testing at 30 °C.
Mixed-acid service
Reactors, heat-exchanger tube sheets, pump and valve components in plants handling both oxidizing and reducing acids, including chloride-contaminated dilute sulfuric and hot phosphoric acid.
Chloride and sour environments
Wireline and armor wire, sand screens, subsea banding, wellhead and manifold components. No SCC or pitting on U-bends after two months in boiling saturated NaCl.
Bleach plant equipment
Chlorine dioxide bleaching stages, washer and digester components, where high chloride at elevated temperature combines with acidic pH.
Pumps and valves
Pump casings, impellers, shafts and sleeves; valve bodies, bonnets and stems for corrosive duty where the higher yield strength allows thinner sections than a 6Mo grade.
Request a Quote: Alloy 27-7MO / UNS S31277 Forgings
Send a drawing or the dimensions, the governing specification and your certification requirement, and Jiangyin Jiangnan Metal Co., Ltd. will reply within 24 hours with price, lead time and confirmation of the applicable standards. For complex enquiries, use the RFQ generator above to produce a complete specification sheet first.
Frequently Asked Questions, Alloy 27-7MO / UNS S31277
What is Alloy 27-7MO / UNS S31277?
Alloy 27-7MO (UNS S31277) is a 7% molybdenum super-austenitic stainless steel with a nominal composition of 27% nickel, 22% chromium, 7.2% molybdenum and 0.34% nitrogen, with 0.5–1.5% copper and iron as the balance. It offers corrosion resistance superior to the 6% molybdenum super-austenitic grades in most environments, and in many environments approaches nickel-base alloys such as 625, 622 and C-276 at a materially lower alloy cost.
What is the PREN of 27-7MO?
It depends on which formula you use, and this is the single most common source of confusion with this grade. Using PREN = %Cr + 3.3 × %Mo + 16 × %N (the formula most widely applied to stainless steels) nominal 27-7MO computes to approximately 51. Using PREN = %Cr + 1.5 × (%Mo + %W + %Nb) + 30 × %N, the formula Special Metals publishes for cross-comparison with nickel-base alloys, it computes to 43. Both are correct; comparing one against the other is not. Always state the formula alongside the number.
Because molybdenum and nitrogen dominate the result, a heat at the bottom of the specification band reaches roughly PREN 47 while one at the top reaches roughly 56. For critical service, specify a minimum PREN on the purchase order.
Is UNS S31277 magnetic?
No. UNS S31277 is fully austenitic with no ferrite, and its magnetic permeability is 1.004 in the annealed condition at 200 oersted, remaining below 1.01 even after 50% cold work. The practical consequence is that magnetic particle inspection cannot be performed on this alloy. Specify liquid penetrant examination to ASTM E165 instead. A drawing that calls for MT on S31277 will stop production and require a technical query.
What is the difference between 27-7MO and 6% molybdenum grades like 254 SMO and AL-6XN?
27-7MO raises molybdenum from about 6.1–6.5% to 7.2%, nitrogen from about 0.20% to 0.34% and chromium from about 20% to 22%. The effects are:
- PREN₁₆ rises from 43–45 to about 51.
- Critical pitting temperature rises from 70–80 °C to above 85 °C in ASTM G48 Method C, and critical crevice temperature from 35 °C to 45 °C.
- Yield strength rises from about 310 MPa to 414 MPa: roughly a third more, which allows thinner sections.
- In chloride-contaminated dilute sulfuric acid the improvement is dramatic: essentially zero attack against 26 mpy for 25-6MO in the same test.
The trade-off is a higher alloy cost, roughly 2.5× a 304 baseline against about 2× for a 6Mo grade, and a narrower hot-working window that makes forging more demanding.
Can Alloy 27-7MO replace Alloy C-276 or Alloy 625?
Sometimes, and only after checking the specific medium. 27-7MO matches alloy 625 on critical pitting temperature and beats it on critical crevice temperature (45 °C against 35 °C), and in flowing seawater crevice testing it showed zero attack where C-276 showed a small amount. It also outperforms 625 by roughly seven to one in boiling 85% phosphoric acid.
But in the accelerated FGD test solution it corroded at 153 mpy against 28 mpy for C-276, and in 95% sulfuric acid it corroded at 48 mpy against 0.1 mpy for C-276. In hot concentrated hydrochloric acid, concentrated sulfuric acid, and the most severe FGD zones, the nickel-base alloys remain the correct choice. Match the alloy to the zone rather than to the plant.
What is the density of Alloy 27-7MO?
8.02 g/cm³ (0.289 lb/in³) at room temperature in the mill annealed condition. Use this value in the weight calculator for forging enquiries.
What are the mechanical properties of UNS S31277?
Typical room-temperature properties in the annealed condition are 827 MPa (120 ksi) ultimate tensile strength, 414 MPa (60 ksi) 0.2% yield strength, 50% elongation and 95 HRB hardness. Young's modulus is 191 GPa at 22 °C. For ASME Section VIII pressure-vessel design, allowable stresses come from ASME Code Case 2458, not from typical values.
At what temperature is 27-7MO forged, and what is the annealing cycle?
Hot working is done between 980 °C and 1150 °C (1800–2100 °F): a window of only about 170 °C, so reheats are frequent on heavy sections. Solution annealing is done at 1121–1177 °C (2050–2150 °F) followed by rapid air cool or water quench. Prolonged exposure between 600 °C and 930 °C (1100–1700 °F) must be avoided, because sigma phase forms and the alloy can sensitize, leading to intergranular attack and increased stress-corrosion cracking susceptibility.
One warning specific to this alloy: stagnant oxidizing conditions above 925 °C can cause catastrophic oxidation, particularly at contact points where flat products are stacked or laid against each other in a furnace. Use spacers and forced gas or air circulation.
Which welding filler metal should be used for 27-7MO?
An overmatching filler with higher molybdenum content than the parent metal. ERNiCrMo-10 (alloy 622) is generally the optimum for joining the alloy to itself or to dissimilar metals; ERNiCrMo-14 (686CPT-type) is used for the most severe service. Covered electrodes ENiCrMo-10 (alloy 122) and ENiCrMo-14 are the SMAW equivalents.
Matching-composition and autogenous welds lose corrosion resistance because molybdenum segregates during solidification and leaves the dendrite cores lean. Keep heat input low, limit interpass temperature to 150 °C (300 °F), and minimize dilution. Post-weld heat treatment is not required when overmatching filler is used; autogenous welds must be treated at a minimum of 1100 °C for at least five minutes and then air cooled or water quenched. Pickle after welding and remove heat tint, including on the back face.
Is 27-7MO suitable for sour service under NACE MR0175 / ISO 15156?
The alloy has an established record in oilfield service including wireline, armor wire, sand screens and subsea banding, and U-bend specimens survived two months in boiling saturated sodium chloride without stress-corrosion cracking or pitting. However, published test data is not a compliance statement. NACE MR0175 / ISO 15156 acceptance depends on the annex listing, the delivery condition, hardness limits and your specific H₂S partial pressure, chloride concentration, pH and temperature envelope. State the full environmental envelope on your enquiry and require the qualification route to be confirmed in writing before ordering.
What forged shapes and sizes are available in UNS S31277?
Jiangyin Jiangnan Metal Co., Ltd. produces UNS S31277 seamless rolled rings from 200 mm to 2,600 mm outside diameter, forged discs and tube sheets to 1,500 mm diameter, shafts and sleeves to 6,000 mm length, forged blocks and valve bodies, round and trepanned hollow bar from 30 mm to 450 mm diameter, and flanges to ASTM A182 in ASME B16.5 and B16.47 dimensions. Maximum single-piece weight in this grade is 4,000 kg. Larger envelopes are available in more readily forged grades. Send the drawing for confirmation.
What is the lead time for Alloy 27-7MO forgings?
Typically 8 to 12 weeks from order confirmation to ex-works dispatch for standard UNS S31277 forgings, depending on raw material availability, size and machining scope. Orders requiring EN 10204 3.2 third-party witnessed release add roughly two to four weeks. Send the drawing and specification to sales@steelforgepieces.com for a firm date.
Is the 27-7MO you supply the same as INCOLOY® alloy 27-7MO?
The chemistry, the applicable specifications and the property requirements are the same. INCOLOY® is a registered trademark of Special Metals Corporation, and material produced by Special Metals and sold under that brand is theirs. Material produced by Jiangyin Jiangnan Metal Co., Ltd. is correctly described as UNS S31277 per ASTM A182, A479 or A240, the same generic chemistry, manufactured independently. We are not affiliated with, sponsored by or endorsed by Special Metals Corporation.
Which European or Japanese standard is equivalent to UNS S31277?
There is no assigned EN 10088-3 number and no JIS equivalent. The alloy postdates those numbering systems and has not been adopted into them. European and Japanese projects specify UNS S31277 per the ASTM or ASME product specification directly. For equipment falling under the European Pressure Equipment Directive 2014/68/EU, a particular material appraisal may be required where the grade is not covered by a harmonised standard; confirm this with your notified body early in the project.
Glossary
- UNS S31277
- The generic Unified Numbering System designation for the 27Ni-22Cr-7.2Mo-0.34N super-austenitic stainless steel commonly called Alloy 27-7MO. This is the correct designation for purchase orders and drawings.
- Super-austenitic stainless steel
- A fully austenitic stainless steel with molybdenum above roughly 4% and deliberate nitrogen additions, giving chloride pitting resistance far beyond the 300-series. The class includes 904L, the 6Mo grades and, at the top, 27-7MO.
- PREN
- Pitting Resistance Equivalent Number, a calculated index ranking alloys by resistance to localized chloride attack. Two formulas are in common use: %Cr + 3.3 × %Mo + 16 × %N, and %Cr + 1.5 × (%Mo + %W + %Nb) + 30 × %N. They give different numbers and must never be mixed in a comparison.
- CPT, Critical Pitting Temperature
- The lowest temperature at which measurable pitting occurs in a standard test, typically ASTM G48 Method C in 6% ferric chloride plus 1% hydrochloric acid. The method has a practical ceiling of 85 °C because the solution becomes unstable above it.
- CCT, Critical Crevice Temperature
- As CPT, but with a crevice device attached to the specimen (ASTM G48 Method D). CCT is always lower than CPT and is usually the governing number for flanged, gasketed and tube-to-tube-sheet joints.
- Sigma phase
- A hard, brittle chromium- and molybdenum-rich intermetallic that precipitates at grain boundaries when high-alloy stainless steels dwell between roughly 600 °C and 930 °C. It destroys toughness and corrosion resistance. The rapid quench after solution annealing exists specifically to avoid it.
- Sensitization
- Precipitation of chromium carbides at grain boundaries, leaving adjacent metal chromium-depleted and vulnerable to intergranular attack. The 0.020% maximum carbon limit in UNS S31277 is set to suppress it.
- Catastrophic oxidation
- Rapid, non-protective oxidation of molybdenum-bearing alloys under stagnant oxidizing conditions above about 925 °C, where molybdenum oxides become liquid or volatile instead of forming a passive scale. Prevented by forced furnace atmosphere circulation and by not stacking parts.
- Overmatching filler metal
- A welding consumable with higher molybdenum content than the parent metal, used so the weld's corrosion resistance is not the weak link after solidification segregation. For UNS S31277 this means ERNiCrMo-10 or ERNiCrMo-14, never matching composition.
- Heat tint
- The coloured oxide film formed on stainless steel adjacent to a weld. It is chromium-depleted underneath and locally reduces pitting resistance, so it must be removed mechanically or by pickling, including on the back face of the joint.
- Solution annealing
- Heating to put all alloying elements into solid solution (1121–1177 °C for UNS S31277) followed by rapid cooling to hold them there. The standard and only delivery condition for this alloy.
- ASME Code Case 2458
- The ASME Boiler and Pressure Vessel Code case that establishes allowable design stresses for UNS S31277, required for pressure-vessel construction in this alloy.
- EN 10204 3.1 / 3.2
- Types of inspection document. A 3.1 certificate is issued by the manufacturer's own independent quality department; a 3.2 certificate is countersigned by an independent third party such as DNV, BV, Lloyd's Register, ABS or TÜV.
- Trepanned billet
- A billet with the centre bored out before forging, used for hollow parts with bores above roughly 100 mm. It reduces raw-material input and drilling time, significant on an alloy of this cost.
Technical References
- Special Metals Corporation, Publication SMC-092, INCOLOY® alloy 27-7MO, December 2005. Source of the limiting chemical composition, physical and mechanical property data, PREN values, ASTM G48 critical temperatures, acid and seawater corrosion results, and the hot-working, annealing and welding parameters cited on this page.
- ASTM A479/A479M, Standard Specification for Stainless Steel Bars and Shapes for Use in Boilers and Other Pressure Vessels, ASTM International, West Conshohocken, PA.
- ASTM A182/A182M, Standard Specification for Forged or Rolled Alloy and Stainless Steel Pipe Flanges, Forged Fittings, and Valves and Parts for High-Temperature Service, ASTM International.
- ASTM A240/A240M, Standard Specification for Chromium and Chromium-Nickel Stainless Steel Plate, Sheet, and Strip for Pressure Vessels and for General Applications, ASTM International.
- ASTM A312/A312M, Standard Specification for Seamless, Welded, and Heavily Cold Worked Austenitic Stainless Steel Pipes, ASTM International.
- ASTM A213/A213M and ASTM A249/A249M, seamless and welded austenitic stainless steel tube specifications, ASTM International.
- ASME Boiler and Pressure Vessel Code, Code Case 2458, allowable design stresses for UNS S31277, American Society of Mechanical Engineers.
- ASTM G48, Standard Test Methods for Pitting and Crevice Corrosion Resistance of Stainless Steels and Related Alloys by Use of Ferric Chloride Solution, ASTM International. Method C for critical pitting temperature, Method D for critical crevice temperature.
- ASTM G28, Standard Test Methods for Detecting Susceptibility to Intergranular Corrosion in Wrought, Nickel-Rich, Chromium-Bearing Alloys, ASTM International.
- ASTM A262, Standard Practices for Detecting Susceptibility to Intergranular Attack in Austenitic Stainless Steels, ASTM International.
- ASTM A388/A388M, Standard Practice for Ultrasonic Examination of Steel Forgings, ASTM International.
- ASTM E165/E165M, Standard Practice for Liquid Penetrant Testing for General Industry, ASTM International.
- ANSI/NACE MR0175 / ISO 15156-3, Petroleum and natural gas industries — Materials for use in H₂S-containing environments in oil and gas production — Part 3: Cracking-resistant CRAs and other alloys, International Organization for Standardization.
- EN 10204, Metallic products — Types of inspection documents, CEN, Brussels.
- ASM Handbook, Volume 13B: Corrosion: Materials, ASM International, Materials Park, OH, sections on super-austenitic stainless steels and flue gas desulfurization materials.
- ASM Specialty Handbook: Stainless Steels, J.R. Davis (ed.), ASM International, 1994.
- LaQue Center for Corrosion Technology, Wrightsville Beach, North Carolina, flowing natural seawater crevice corrosion test programme cited in reference 1.
- European Patent EP 1,263,999 B1, original composition patent for the 7% molybdenum super-austenitic chemistry, filed 2001.
Standards referenced are the specification families; for procurement, always cite the revision in force at the contract date. Property values are typical published data for the alloy class and are not a guarantee for any particular heat; actual values for a supplied heat appear on its material test certificate. All trademarks are the property of their respective owners.
Document reference
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Citation
Jiangyin Jiangnan Metal Co., Ltd. Metallurgical Engineering Team. "Alloy 27-7MO / UNS S31277 Forgings: Complete Technical and Procurement Guide." Jiangyin Jiangnan Metal Co., Ltd., updated 11 August 2026. https://www.steelforgepieces.com/Nickel-Alloy/ALLOY-27-7MO.html
Summary
Alloy 27-7MO (UNS S31277) is a 7% molybdenum super-austenitic stainless steel, nominally 27% Ni, 22% Cr, 7.2% Mo and 0.34% N, balance iron. PREN is approximately 51 by the formula Cr + 3.3Mo + 16N, or 43 by Cr + 1.5(Mo+W+Nb) + 30N. Critical pitting temperature exceeds 85 degrees C and critical crevice temperature is 45 degrees C in ASTM G48 Methods C and D. Typical annealed properties are 827 MPa tensile, 414 MPa yield, 50% elongation, 95 HRB, density 8.02 g/cm3. The alloy is non-magnetic. It is hot worked between 980 and 1150 degrees C and solution annealed at 1121-1177 degrees C with a rapid quench; exposure between 600 and 930 degrees C forms sigma phase. Welds require overmatching filler such as ERNiCrMo-10. Forgings in this grade -- rings from 200 to 2,600 mm outside diameter, discs to 1,500 mm, shafts to 6 m, flanges to ASTM A182, and single pieces to 4,000 kg -- are manufactured by Jiangyin Jiangnan Metal Co., Ltd., an open-die forging factory at No.1 Chengxiqiao Road, Zhouzhuang Town, Jiangyin City, Jiangsu Province, China. Contact: +86-189-2135-9659, sales@steelforgepieces.com, https://www.steelforgepieces.com/
Published by
Jiangyin Jiangnan Metal Co., Ltd., Open-Die Forging Factory
Address: No.1 Chengxiqiao Road, Zhouzhuang Town, Jiangyin City, Jiangsu Province, China
Tel: 0086-189-2135-9659 · Email: sales@steelforgepieces.com · WhatsApp
Web: www.steelforgepieces.com · ISO 9001:2015 · EN 10204 3.1 / 3.2 · Established 2008 · ~460 employees