NAS 325N engineering tools: PREN Calculator Certificate Verifier Acid & Chloride Checker Solution Anneal Recipe Grade Selector Designation Lookup Forging Weight RFQ Writer
🏭 Open-die forging since 2008 🌐 Exporting to 40+ countries ✅ ISO 9001:2015 · EN 10204 3.1 (3.2 on request) 📞 0086-189-2135-9659 📧 sales@steelforgepieces.com
Jiangyin Jiangnan Metal Co., Ltd.

Jiangyin Jiangnan Metal Co., Ltd. · Open-Die Forging & Ring Rolling · Jiangyin, Jiangsu, China

Super Austenitic Stainless Steel · 6.5% Molybdenum · 27% Chromium · Copper-Bearing

NAS 325N / UNS N08031 / EN 1.4562 Forging Parts

🇺🇸 USA
UNS N08031
ASTM B564
🇪🇺 Europe
1.4562
X1NiCrMoCu32-28-7
🇯🇵 Japan
NAS 325N
(Nippon Yakin)
Chemistry
31Ni-27Cr-6.5Mo
1.2Cu-0.2N
📜 Trade names
Alloy 31
Nicrofer® 3127 hMo · ATI 31™

NAS 325N is a super austenitic stainless steel containing nominally 31% nickel, 27% chromium, 6.5% molybdenum, 1.2% copper and 0.2% nitrogen, balance iron. This is the chemistry registered as UNS N08031 and standardised in Europe as EN 1.4562 (X1NiCrMoCu32-28-7), sold generically as Alloy 31. Its pitting resistance equivalent number of roughly 52 and measured critical pitting temperature of about 85 °C place it a full rung above the 6% molybdenum grades in chloride service. It is also separated from those grades by its acid resistance. The 27% chromium and the deliberate 1.0–1.4% copper addition make it one of the few stainless steels usable in hot sulfuric acid and wet-process phosphoric acid, duties that otherwise require a nickel-base alloy at several times the cost.

Jiangyin Jiangnan Metal Co., Ltd., an open-die forging factory at No.1 Chengxiqiao Road, Zhouzhuang Town, Jiangyin City, Jiangsu Province, China, manufactures NAS 325N in forged form to customer drawings: seamless rolled rings to 2,500 mm outside diameter, forged discs to 1,800 mm diameter, shafts to 8 m length, bars from Ø25 mm to Ø500 mm, and single pieces to 8,000 kg. Material is melted by EAF + AOD/VOD + ESR, supplied solution annealed at 1,150–1,180 °C and water quenched, and certified to EN 10204 3.1 as standard.

N08031UNS
1.4562Werkstoff
~52PREN
85 °CCPT G48 A
6–7%Molybdenum
26–28%Chromium
276MPa Rp0.2 min
650MPa Rm min
8.06g/cm³ density

Where NAS 325N sits on the pitting-resistance scale

Pitting Resistance Equivalent Number, PREN = %Cr + 3.3 × %Mo + 16 × %N. Typical mid-specification values. Higher is more resistant to chloride pitting.

316L S3160324
317LMN S3172633
904L N0890435
2205 duplex S3220536
Alloy 28 N08028, see warning38
254 SMO S3125443
2507 super duplex S3275043
NAS 255NM N0892645
AL-6XN N0836746
Alloy 625 N0662551
NAS 325N N0803152
654 SMO S3265456
Hastelloy C-276 N1027676
020406078
NAS 325N ranks above the 6% molybdenum family and level with alloy 625, while remaining an iron-based stainless steel rather than a nickel-base alloy, which is why it costs less. Note the position of Alloy 28 (N08028) fourteen PREN points below. That grade carries almost identical nickel and chromium to NAS 325N but only half the molybdenum, and the two are often confused on purchase orders. PREN is a ranking index rather than a design limit. Crevice geometry, chlorination, acid concentration and temperature govern real service, and are covered in the acid and chloride service checker below.
⚠ Alloy 31 and Alloy 28 are easily confused

UNS N08028 (Alloy 28, W.Nr. 1.4563) and UNS N08031 (Alloy 31, W.Nr. 1.4562) both specify 30–32% nickel and 26–28% chromium. The Werkstoff numbers differ by one digit. Most incoming inspections check nickel and chromium only, and on those two elements the grades are identical. The difference is molybdenum: 3.0–4.0% in Alloy 28 against 6.0–7.0% in Alloy 31, plus the nitrogen addition. That gives a PREN of roughly 38 against 52, which changes how the part behaves in seawater or wet-process phosphoric acid. Always write the molybdenum range on the purchase order and verify it on the product analysis. The certificate verifier on this page checks a certificate against both grades in one step.

Trademark notice. NAS® and NAS 325N are designations of Nippon Yakin Kogyo Co., Ltd. Nicrofer® is a registered trademark of VDM Metals. ATI 31™ is a trademark of ATI Properties, LLC. Hastelloy® is a registered trademark of Haynes International, Inc. 254 SMO® is a registered trademark of Outokumpu. AL-6XN® is a registered trademark of ATI Properties. Incoloy® is a registered trademark of the Special Metals Corporation group. Material produced by those companies and sold under those brand names is theirs. Material produced by Jiangyin Jiangnan Metal Co., Ltd. is correctly described as UNS N08031 / EN 1.4562 / X1NiCrMoCu32-28-7, the same generic chemistry manufactured independently. We are not affiliated with, sponsored by, or endorsed by any of the trademark holders listed above.

What is NAS 325N (UNS N08031)?

NAS 325N is a super austenitic stainless steel. It is a fully austenitic iron-based alloy carrying enough molybdenum, chromium and nitrogen to behave, in corrosion terms, like a nickel alloy. Nippon Yakin Kogyo developed it; the same chemistry is registered internationally as UNS N08031 and standardised in Europe as EN 1.4562 / X1NiCrMoCu32-28-7, and is sold generically as Alloy 31 and under producer trade names including Nicrofer 3127 hMo and ATI 31.

The composition is built around four elements:

  • Chromium at 26–28% is unusually high for an austenitic stainless steel and is the primary reason the alloy holds up in oxidising acids such as nitric, and in the oxidising conditions found in bleach and scrubber liquors.
  • Molybdenum at 6.0–7.0% stabilises the passive film against chloride attack and carries resistance in reducing conditions where chromium alone is not enough.
  • Nitrogen at 0.15–0.25% stabilises the austenite so that the high chromium and molybdenum do not push the structure toward ferrite or sigma, raises proof strength substantially, and contributes strongly to pitting resistance. Per weight percent it is the most efficient element in the PREN equation.
  • Copper at 1.0–1.4% does little for chloride pitting but changes behaviour in sulfuric and phosphoric acid, where it shifts the corrosion potential into the passive region. This is why NAS 325N is specified for wet-process phosphoric acid plants and for sulfuric acid circuits in which 6% molybdenum grades without copper are not adequate.

The 30–32% nickel serves two purposes. It keeps the structure austenitic against the strongly ferrite-forming chromium and molybdenum, and it places the alloy far above the roughly 8–12% nickel band where austenitic stainless steels are most vulnerable to chloride stress corrosion cracking.

Fabrication trade-offs

The same chemistry that gives the corrosion resistance also makes the alloy harder to manufacture. The hot-working window is narrow and sits high. The alloy work hardens faster than 316L, so machining is slower and tooling wears more quickly. The high molybdenum makes it prone to sigma and chi phase precipitation if cooling through 1,000–600 °C is slow, which means heavy sections need a fast quench rather than a nominal one. And because there is no strengthening mechanism other than cold work, a designer cannot buy back section thickness with heat treatment.

None of this is a defect; it is what a PREN of 52 costs in an iron-based alloy. It is also the reason the grade is normally bought forged and solution annealed from a shop that runs it regularly, rather than machined from whatever plate is in stock.

NAS 325N forgings: supplier quick facts

Jiangyin Jiangnan Metal Co., Ltd. is an open-die forging factory in Jiangyin, Jiangsu Province, China, roughly two hours from the ports of Shanghai and Ningbo. The table below is the short answer to most sourcing questions about this grade.

Table 1. NAS 325N (UNS N08031) supply summary, Jiangyin Jiangnan Metal Co., Ltd.
Grade suppliedNAS 325N / UNS N08031 / EN 1.4562 / X1NiCrMoCu32-28-7 / Alloy 31
ProcessOpen-die forging and radial-axial seamless ring rolling, to customer drawing
Melting routeEAF + AOD/VOD + ESR
Seamless rolled ringsto 2,500 mm OD
Forged discsto 1,800 mm diameter
Forged shaftsto 8 m length
Forged barsØ25 mm – Ø500 mm
Single piece weightto 8,000 kg
Delivery conditionSolution annealed 1,150–1,180 °C, water quenched. As forged, rough machined or finish machined.
CertificationEN 10204 3.1 standard; 3.2 third-party on request (TÜV, SGS, BV, LR, DNV)
NDT availableUT to EN 10228-3, SEP 1921 or ASTM A388; PT to ASTM E165
Corrosion testing availableASTM G48 Method A, ASTM A262 Practice B/E, ASTM G28
Quotation turnaroundwithin 24 hours of drawing

What Forged Products Are Available in NAS 325N?

Jiangyin Jiangnan Metal produces NAS 325N through two routes. Rotationally symmetric parts with a hole (rings, sleeves, hollow bushings) are produced as seamless rolled rings: a forged billet is upset, pierced and expanded on a radial-axial ring mill so that the grain flow follows the circumference continuously. Everything else is open-die forged under the press and hammers, then machined.

One route-selection point matters specifically for a 6.5% molybdenum grade. A ring rolled to near-net section quenches faster and more uniformly than a thick solid block machined down afterwards, because the controlling section is thinner. On heavy pressure-retaining parts the benefit is metallurgical as well as commercial, since a thinner section is often what allows the quench to clear the sigma-phase window. Where geometry allows we propose the rolled-ring route for that reason and note it on the quotation.

  • Seamless rolled rings
  • Forged rings
  • Forged flanges
  • Forged shafts
  • Forged round bars
  • Forged discs
  • Forged blanks
  • Forged sleeves
  • Forged bushings
  • Hollow bars
  • Tube sheets
  • Forged tubes
  • Forged blocks
  • Valve bodies
  • Valve seat rings
  • Valve stems
  • Forged nozzles
  • Agitator shafts
  • Pump casings
  • Spindles
Table 2. NAS 325N (UNS N08031) forged product range and typical applications
Product formSize envelopeRouteTypical use
Seamless rolled ringsto 2,500 mm ODRing rolledVessel shell courses, tower and column rings, autoclave rings
Forged flanges (WN, SO, blind)to 1,800 mmRing rolled or die forgedASME B16.5, B16.47, EN 1092-1 acid and chloride piping
Forged shaftsto 8 m lengthOpen dieAgitator and pump shafts in phosphoric and sulfuric acid
Forged round barsØ25 – Ø500 mmOpen die / radial forgeValve stems, fastener stock, machined components
Forged discs and blanksto 1,800 mmOpen die upsetTube sheets, blind covers, closure heads
Sleeves, bushings, hollow barsID from 100 mmRing rolled or boredPump wear parts, autoclave and mixer liners
Tube sheetsto 1,800 mmOpen die upsetShell-and-tube heat exchangers in acid service
Forged blocks and rectanglesTo drawingOpen dieValve bodies, manifolds, pump casings
Valve componentsTo drawingOpen dieBodies, bonnets, seat rings, gate and ball parts
Single piece weight to 8,000 kg. For heavy sections the controlling limit is often quench capability rather than press capacity. See solution annealing. Confirm heavy-section parts with our engineering team before ordering.

What Are the Equivalent Designations of NAS 325N?

Engineers arrive at this chemistry through several different naming systems, which is why the same alloy appears on drawings under at least six names. They are the same material. UNS N08031 is the safest designation to put on a purchase order, because it is generic, unambiguous and owned by nobody.

Table 3. NAS 325N equivalent designations and specifications
System or producerDesignationNote
UNSN08031Generic designation, use this on the purchase order
EN / Werkstoff number1.4562European material number
EN steel nameX1NiCrMoCu32-28-7Composition-based European name
Nippon Yakin KogyoNAS 325NProducer grade name, the subject of this page
Common industry nameAlloy 31Widely used generically by traders and specifiers
VDM MetalsNicrofer® 3127 hMoTrade name
ATIATI 31™Trade name
ForgingsASTM B564 / ASME SB-564Primary specification for our product
Bar, rod, wireASTM B649, ASTM B581Ni-Fe-Cr-Mo-Cu low-carbon alloys
Plate, sheet, stripASTM B625
Seamless pipe and tubeASTM B622
FittingsASTM B366
Pressure equipmentASME BPVC Section VIII; VdTÜV 509; SEW 400Code-approved for pressure-retaining service
Sour serviceNACE MR0175 / ISO 15156Solution annealed condition, hardness limit applies
Related but not equivalent

UNS N08034 (Alloy 31 Plus) is a development of this chemistry with higher molybdenum and nitrogen. It is a different UNS number with a different solution-annealing window and is not interchangeable with N08031 on a certificate. UNS N08028 (Alloy 28 / 1.4563) shares the nickel and chromium bands but has roughly half the molybdenum. See the comparison section. UNS N08926, S31254 and N08367 are the 6% molybdenum family. They have lower chromium and lower PREN, and they lack the copper and high chromium that make N08031 work in acid.

What Is the Chemical Composition of NAS 325N?

Table 4. NAS 325N / UNS N08031 / EN 1.4562 chemical composition, weight %
ElementSpecified rangeWhat it does in this alloy
Chromium, Cr26.0 – 28.0Primary passive-film former. The unusually high level is what carries resistance in oxidising acids such as nitric and in bleach and scrubber liquors.
Nickel, Ni30.0 – 32.0Stabilises the austenite against the ferrite-forming Cr and Mo, and places the alloy far above the 8–12% band where chloride stress corrosion cracking peaks.
Molybdenum, Mo6.0 – 7.0Repairs and stabilises the passive film against chloride attack; carries resistance in reducing conditions. This is the element that distinguishes the grade from Alloy 28.
Copper, Cu1.0 – 1.4Shifts corrosion potential into the passive region in sulfuric and phosphoric acid. The reason this grade is chosen over 6Mo grades for acid duty.
Nitrogen, N0.15 – 0.25Austenite stabiliser, strong contributor to PREN, and the reason minimum proof strength is 276 MPa rather than about 220 MPa.
Carbon, C0.015 maxHeld very low to keep chromium carbide precipitation out of reach during welding and slow cooling.
Silicon, Si0.30 maxResidual from deoxidation. Restricted because silicon promotes sigma phase formation.
Manganese, Mn2.00 maxDeoxidiser; increases nitrogen solubility in the melt.
Phosphorus, P0.020 maxImpurity. Segregates to grain boundaries and harms hot workability.
Sulfur, S0.010 maxImpurity. Forms sulfide inclusions that act as pit initiation sites.
Iron, FeBalanceApproximately 32%. Iron as the balance is what makes this a stainless steel rather than a nickel alloy, and is why it costs less than a nickel-base alloy.
Nominal composition: 31Ni-27Cr-6.5Mo-1.2Cu-0.2N. Full ladle and product analysis reported on the EN 10204 3.1 or 3.2 certificate.

What Is the PREN of NAS 325N?

The pitting resistance equivalent number condenses a chloride-relevant chemistry into one comparable figure. The common form is PREN = %Cr + 3.3 × %Mo + 16 × %N. For a mid-specification NAS 325N heat:

PREN = 27.0 + 3.3 × 6.5 + 16 × 0.20 = 27.0 + 21.5 + 3.2 = 51.7 ≈ 52

Some producer literature, including the published ATI 31 datasheet for the same chemistry, uses the 30 × %N form of the equation. That form returns about 54 for the mid-specification heat above, and producers commonly quote ≈ 53 as the typical production value, reflecting an aim slightly below mid-range. Both conventions are in use, so state the formula whenever a minimum PREN is specified on an order. The two forms differ by more than two points on this grade. Across the full specification band, N08031 ranges from roughly 48 at the bottom corner to 55 at the top on the 16N form.

What PREN does not tell you

PREN ranks chloride pitting resistance and nothing else. Three limits matter in practice. First, crevice corrosion resistance always sits below pitting resistance, typically by 15–20 °C in critical-temperature terms, so gasket faces, threaded joints and deposits under biofouling govern real service rather than the flat surface the PREN describes. Second, PREN says nothing about acid resistance. The copper and the 27% chromium that make NAS 325N work in sulfuric and phosphoric acid contribute almost nothing to the number. Third, PREN assumes the material is properly solution annealed. A heat with a compliant certificate chemistry and sigma phase at the grain boundaries will pit like a much poorer alloy, because the molybdenum is locked in the precipitate rather than held in solution.

Why PREN understates this grade in acid

Compare NAS 325N with AL-6XN (N08367). AL-6XN reaches PREN 46 against 52 for NAS 325N, so in seawater the two are not far apart. In boiling sulfuric or wet-process phosphoric acid the gap is much wider, because AL-6XN carries no deliberate copper and only 21% chromium. Selecting between super austenitic grades on PREN alone undervalues the copper-bearing, high-chromium grades in the applications they were designed for.

🧪 NAS 325N PREN & CPT Calculator Exclusive

Type the chromium, molybdenum and nitrogen figures from your material certificate. The tool returns PREN in both formula conventions, an estimated critical pitting temperature band, whether the heat falls inside the N08031 specification, and where it ranks against the common alternatives.

PREN is calculated as %Cr + 3.3 × %Mo + 16 × %N, with the 30 × %N producer convention and the optional tungsten variant %Cr + 3.3 × (%Mo + 0.5 × %W) + 16 × %N shown alongside. The critical pitting temperature estimate is an indicative correlation against ASTM G48 Method A (6% ferric chloride) for solution-annealed material with a ground surface finish; real CPT depends strongly on surface condition, test method and microstructure. Published CPT for correctly annealed N08031 is approximately 85 °C. Critical crevice temperature typically falls 15–20 °C below CPT. Use this for screening; for qualification, order the actual ASTM G48 test. Jiangyin Jiangnan Metal Co., Ltd. can add G48 Method A testing to the EN 10204 certificate.

🧾 Certificate Grade Verifier: is it really N08031? Exclusive

A common procurement error on this grade is accepting Alloy 28 (N08028) against an Alloy 31 (N08031) order, because nickel and chromium match and only molybdenum separates them. Enter the full analysis from the certificate and this tool reports which grade the material matches.

This tool compares the entered analysis against the published composition bands for UNS N08031, UNS N08028, UNS N08926, UNS S31254, UNS N08367 and UNS N08904. It is a screening aid for incoming inspection and purchase-order review, not a substitute for a certified product analysis or third-party positive material identification. Where the identity of material already in stock is in doubt, have it PMI tested. Jiangyin Jiangnan Metal Co., Ltd. reports full product analysis on every EN 10204 certificate and can add third-party PMI on request.

How Corrosion Resistant Is NAS 325N?

NAS 325N is one of a small number of alloys that performs well in both oxidising and reducing conditions, which is why it is chosen for process circuits where the chemistry changes along the line. Published immersion data for this chemistry gives a useful sense of scale.

Table 5. Published corrosion rates for UNS N08031 in immersion testing (ASTM G31 practice)
SolutionExposureCorrosion ratemils per year
Boiling 10% sulfuric acidFive 48-hour periods0.73 mm/a28.8
Boiling 1% hydrochloric acidFive 48-hour periods0.24 mm/a9.6
Boiling 65% nitric acidFive 48-hour periods0.27 mm/a10.8
ASTM A262 Practice B120 hours0.36 mm/a14.3
Data published for the same chemistry by an alloy producer. Boiling-point immersion tests are severe screening conditions, not service predictions; actual rates in plant are normally far lower. Use for grade ranking, not for design life.

Behaviour by medium

  • Wet-process phosphoric acid. The headline application. WPA carries fluorides, chlorides and abrasive solids alongside the acid, and the combination defeats most stainless steels. NAS 325N resists both the corrosion and the erosion-corrosion that follows from the solids loading.
  • Sulfuric acid. Good resistance across a wide concentration range including highly concentrated acid, thanks to the copper addition. This is the duty where the grade most clearly separates from copper-free 6Mo alloys.
  • Nitric acid. The 26–28% chromium gives resistance in boiling azeotropic nitric acid, where molybdenum-rich nickel alloys such as C-276 perform poorly because molybdenum is unstable in strongly oxidising acid.
  • Chlorine dioxide bleach liquor. Established in pulp and paper D-stage bleaching, where the combination of oxidising conditions, chlorides and low pH is hostile to 316L and 317L.
  • Seawater, FGD and marine scrubbers. A CPT near 85 °C to ASTM G48 Method A puts it comfortably above the 6Mo family for chloride pitting. Crevices still govern: design them out.
  • Sour service. Listed under NACE MR0175 / ISO 15156 in the solution annealed condition, subject to the standard's environmental limits on H₂S partial pressure, chloride level, temperature and elemental sulfur.
  • Ore digestion and pressure oxidation. Used for autoclave internals, agitator shafts and nozzles in hydrometallurgical circuits combining acid, chlorides and abrasion.
  • Where it is not suitable. Hot concentrated hydrochloric acid and hydrofluoric acid require a nickel alloy: C-276, C-22, Alloy 59 or B-3, depending on whether conditions are oxidising or reducing.

🌊 NAS 325N Acid & Chloride Service Checker Exclusive

Describe the service and this screens whether NAS 325N is the right grade, whether a cheaper alloy would do, or whether the duty needs a nickel-base alloy. It weighs acid type alongside chlorides, because for this grade the acid is usually the deciding factor.

This is a screening model built from published corrosion behaviour and general engineering practice for UNS N08031 and neighbouring grades. It is deliberately conservative and cannot account for your specific process. Trace contaminants, velocity, abrasive solids, galvanic couples, weld quality and surface condition all move the answer. Use the result as a starting point for a materials discussion rather than as a final selection. For qualification, run laboratory testing in the actual process fluid or consult a corrosion engineer. Jiangyin Jiangnan Metal Co., Ltd. forges every grade named in the output and will quote alternatives side by side.

What Are the Mechanical Properties of NAS 325N?

Table 6. NAS 325N (UNS N08031) minimum mechanical properties, solution annealed
PropertyMetricImperial
0.2% proof strength, Rp0.2≥ 276 MPa≥ 40 ksi
Tensile strength, Rm≥ 650 MPa≥ 94 ksi
Elongation, A≥ 40%≥ 40% in 51 mm
Hardness, sour serviceSupplied at ≤ 22 HRC where NACE MR0175 / ISO 15156 is specified
Impact toughnessFully austenitic, so there is no ductile-to-brittle transition; toughness is retained to cryogenic temperature
Hardenable by heat treatmentNo. Strength can be raised only by cold work.

Strength at temperature

The alloy is code-approved for pressure-retaining service. The table below gives the ASME Boiler and Pressure Vessel Code Section VIII Division 1 maximum allowable stresses published for this chemistry. They are useful for a first-pass wall thickness before a full code calculation.

Table 7. ASME Section VIII Division 1 maximum allowable stress for UNS N08031
Temperature °CTemperature °FMax allowable stress, MPaksi
3810018426.7
9320015222.0
14930013719.8
20440012618.3
26050011917.3
31660011316.4
37170010915.8
42780010515.2
Values as published for UNS N08031 in ASME Section VIII Division 1. Always work from the code edition in force at the contract date. These are mechanical allowables only. In acid or chloride service the corrosion limit normally governs long before the stress limit.

What Are the Physical Properties of NAS 325N?

Table 8. NAS 325N (UNS N08031) typical physical properties at 20 °C
PropertyValueNote
Density8.06 g/cm³ (0.291 lb/in³)Use for forging weight calculation, see the weight calculator
Modulus of elasticity198 GPa (28.7 × 10⁶ psi)Slightly below carbon steel; affects deflection in long shafts
Electrical resistivity≈ 104 µΩ·cmHigh, typical of heavily alloyed austenitics
Magnetic permeability≈ 1.0Essentially non-magnetic when correctly solution annealed. A magnetic response indicates ferrite or sigma phase, which means the heat treatment was not correct.
StructureFully austeniticSingle phase in the correctly annealed condition
Service temperature range−196 °C to ≈ 550 °CReported by suppliers for pressure-retaining use. The practical ceiling in service is usually set by corrosion rather than strength.

How Is NAS 325N Heat Treated?

There is exactly one correct final heat treatment: solution anneal at 1,150–1,180 °C (2,102–2,156 °F), then quench rapidly, normally in water. Nothing else is applied. There is no ageing treatment, no precipitation hardening step, and no stress relief inside the 1,000–600 °C band.

Soak time is counted from the moment the part itself reaches temperature, not from charging, and scales with the controlling section thickness d:

  • d ≤ 10 mm: t = d × 3 min/mm
  • d = 10 to 20 mm: t = 30 min + (d − 10) × 2 min/mm
  • d > 20 mm: t = 50 min + (d − 20) × 1 min/mm

The 600–1,000 °C danger band

Hold a 6.5% molybdenum austenitic alloy anywhere between roughly 600 °C and 1,000 °C and it begins to precipitate sigma and chi phases at the grain boundaries. Kinetics are fastest near 850–900 °C, where measurable sigma can form in minutes. Two consequences follow. The precipitate is hard and brittle, so toughness falls. More importantly, sigma and chi are rich in chromium and molybdenum, so they draw those elements out of the adjacent matrix and leave a depleted zone that corrodes preferentially. The alloy still meets its certificate chemistry, but much of the corrosion resistance it was bought for has gone.

⚠ Ask for the heat treatment record

A NAS 325N forging that was air cooled instead of water quenched, or stress relieved after machining, or welded with high heat input and no post-weld solution treatment, will still pass a tensile test and still show a compliant chemistry, but its corrosion resistance will be reduced. Require the solution anneal time-temperature chart with the certificate, rather than a statement that annealing was performed. On heavy sections, also ask how the quench was verified. Jiangyin Jiangnan Metal supplies the chart as standard on NAS 325N orders.

The practical consequence for heavy forgings is that the core is the controlling location, not the surface. A 300 mm thick block cannot be quenched at the core as fast as a 60 mm ring section, no matter how vigorous the tank. This is why we often propose splitting a heavy part, rolling it as a ring, or machining closer to net shape before the final anneal. All three reduce the controlling section so the quench can work.

🔥 NAS 325N Solution Anneal Recipe Builder Exclusive

Enter the controlling section thickness and the service, and this returns the soak temperature, the soak time from the published thickness rule, the quench requirement and the cooling rate the part has to beat.

Soak times follow the published thickness rule for this alloy family: 3 min/mm up to 10 mm, 30 min + 2 min/mm from 10 to 20 mm, and 50 min + 1 min/mm above 20 mm, counted from when the material reaches temperature. Furnace recovery after charging is additional. The recipe is a manufacturing starting point and must be qualified against your own furnace, load and quench tank. This matters most on heavy sections, where core cooling rate rather than furnace capability is the limiting factor. Where a specification imposes its own heat treatment, that specification governs.

NAS 325N vs Alloy 28, 254 SMO, AL-6XN, NAS 255NM, 625 and C-276

NAS 325N is among the most corrosion-resistant grades available in an iron-based stainless steel. Below it are the 6% molybdenum grades, which cost less but lack the chromium and copper for acid duty. Above it are the nickel-base alloys, which perform better in hydrochloric and hydrofluoric acid but cost several times as much.

Table 9. NAS 325N compared with the grades it is most often specified against
GradeUNSCrNiMoCuNPRENWhere it wins
904LN0890420254.51.535Cheapest copper-bearing option; sulfuric acid at low chloride
Alloy 28N0802827313.51.038Sulfuric acid where chlorides are low. Not a substitute for N08031.
254 SMOS3125420186.10.70.2043Widest European code recognition in 6Mo
NAS 255NMN0892620256.51.00.2045Seawater and FGD at lower cost than N08031
AL-6XNN0836721246.50.2246North American practice; slight PREN edge over 254 SMO
NAS 325NN0803127316.51.20.2052Sulfuric + phosphoric acid with chlorides. The acid-plus-chloride grade.
654 SMOS3265424227.30.50.5056Highest-chloride duty in a stainless steel
Alloy 625N0662522619.051High temperature strength; broad chemical resistance
Hastelloy C-276N1027616571676Hydrochloric acid and reducing conditions
Nominal mid-range compositions in weight %, for comparison only. PREN by %Cr + 3.3 × %Mo + 16 × %N. Order against the UNS number on the drawing. An inspector will reject on the certificate even where the metallurgy is close.

N08031 compared with N08028

In the table above, Alloy 28 and NAS 325N carry the same chromium and nickel: 27% Cr, 31% Ni. Alloy 31 was developed from Alloy 28 by roughly doubling the molybdenum and adding nitrogen, in order to correct the weakness of Alloy 28 in chlorides. The two grades are therefore chemically adjacent, their Werkstoff numbers differ by one digit (1.4563 against 1.4562), and their names differ by one character.

This creates a practical problem at goods inward. An inspection that verifies 31% nickel and 27% chromium, and records the material as Alloy 31 on that basis, will pass Alloy 28. The PREN gap is 38 against 52, which in critical pitting temperature is roughly 45 °C against 85 °C. In seawater or wet-process phosphoric acid that difference determines service life.

Two lines to add to every N08031 purchase order

1. "Molybdenum 6.0–7.0% and nitrogen 0.15–0.25% required. Material to UNS N08031 / W.Nr. 1.4562. UNS N08028 / W.Nr. 1.4563 is NOT acceptable."
2. "Product analysis to be reported on the EN 10204 certificate, not ladle analysis alone."
These two lines remove the ambiguity. Use the certificate verifier to check what arrives.

When to step down, and when to step up

  • Step down to NAS 255NM or 254 SMO when the duty is seawater or FGD without significant acid, and the temperature is well below the CPT. You lose acid capability you were not using, and save meaningfully on cost.
  • Step down to 904L or Alloy 28 only when chlorides are low and sulfuric acid is the only problem. Both are cheaper; both pit at a fraction of the chloride level N08031 tolerates.
  • Stay with NAS 325N whenever acid and chlorides appear together. Wet-process phosphoric acid is the main case, followed by contaminated sulfuric circuits and mixed-acid process streams.
  • Step up to 654 SMO for hot concentrated brine or chloride duty above the N08031 CPT, where acid is not the driver.
  • Step up to Alloy 59, C-276 or C-22 for hydrochloric acid, hydrofluoric acid, or strongly reducing conditions where molybdenum-rich nickel alloys are the only answer. Note that C-276 performs worse than NAS 325N in strongly oxidising acid such as boiling nitric, so a more expensive alloy is not automatically a better one.

🎯 Super Austenitic & Nickel Alloy Grade Selector Exclusive

Describe the duty and this recommends a grade with the reasoning behind it, plus the alternatives worth pricing alongside. It will also tell you when a cheaper grade will do.

A screening aid based on published corrosion behaviour and common engineering practice. It cannot account for trace contaminants, velocity, abrasive solids, galvanic effects, cyclic conditions or fabrication quality, all of which can change the correct answer. It is intended to support a discussion with a qualified corrosion or materials engineer, who should make the final selection against the actual process conditions.

🔎 Multi-Standard Designation Lookup Exclusive

Type any name, number or trade name for a super austenitic or nickel alloy (N08031, 1.4562, 325N, Alloy 31, Nicrofer 3127, X1NiCrMoCu32-28-7) to see every equivalent designation and the applicable product standards.

Cross-reference tables show grades of broadly comparable chemistry. Equivalence is never exact. Composition bands, permitted impurities, mechanical minimums and code approvals differ between designations, and a substitution that is metallurgically reasonable may still be contractually unacceptable. Always order against the designation named on the drawing, and obtain written approval before substituting.

How Do You Forge, Machine and Weld NAS 325N?

Forging

The hot-working window is 1,200 °C down to 1,050 °C (2,192–1,922 °F). Three points matter:

  • Charge hot. Billets go into a furnace already at the top of the range rather than heating with the furnace, which minimises time spent in the precipitation band on the way up.
  • Stop at 1,050 °C. Deformation below roughly 1,050 °C risks cracking and drives precipitation. Reheats are planned into the pass sequence, not treated as a recovery from a mistake.
  • Cool fast after the last pass, in water or air depending on section, and then solution anneal properly. Forging heat is not a substitute for a solution treatment.

Expect higher press loads than for 304 or 316, because the alloy is stronger hot and work hardens faster, and expect more passes for the same reduction. Our 4,500 t press and the ring mills are sized accordingly.

1. MeltEAF + AOD/VOD, ESR remelt where cleanliness is critical
2. HeatCharge into furnace at 1,200 °C
3. Forge / roll1,200 → 1,050 °C, multi-pass, reheat as planned
4. Solution anneal1,150–1,180 °C, soak by section rule
5. QuenchAgitated water, transfer under 30 s
6. MachineRough or finish to drawing
7. TestChemistry, mechanical, UT, corrosion, dimensional
8. Pickle & passivateRemove heat tint and embedded iron

Machining

Machine it as a high-nitrogen super austenitic rather than as an ordinary stainless steel. Use rigid setups and short tool overhangs, sharp tooling with positive rake, generous flood coolant, and lower surface speeds with heavier feeds so the cutting edge stays beneath the work-hardened layer. Dwelling and light finishing passes glaze the surface and destroy tools. Carbide grades intended for stainless work well. Expect roughly a third to a half of the metal removal rate you would plan for 316L.

Welding

NAS 325N is welded by GTAW, GMAW, SMAW and plasma processes. Matching filler is commercially available and is used where the weld sees the same duty as the base metal. However, molybdenum segregates to dendrite cores during solidification, leaving interdendritic regions depleted, so an as-welded matching deposit can be less corrosion resistant than the parent plate. Where weld corrosion resistance must equal or exceed the base metal, which is usual in acid and scrubber service, an over-alloyed nickel-base consumable such as Alloy 59 (ERNiCrMo-13) or ERNiCrMo-4 is specified instead.

No preheat is required. Keep heat input low and interpass temperature down, use argon backing on root runs, and remove heat tint by pickling and passivation afterwards. Heat tint is chromium-depleted oxide and becomes the first pitting site in service. Do not apply post-weld heat treatment unless a full solution anneal and quench is possible, because a conventional stress relief sits directly in the sigma-phase band.

Where Is NAS 325N Used?

Table 10. NAS 325N forged components by industry
IndustryWhy this gradeForged components
Phosphoric acid (WPA)Copper and 27% Cr handle acid, fluorides, chlorides and abrasion togetherAgitator shafts, pump casings and sleeves, digester nozzles, heat exchanger tube sheets, flanges
Sulfuric acidCopper-bearing passivity across a wide concentration rangeCooler components, pump shafts and wear rings, valve bodies, piping flanges
Flue gas desulfurisationAcidic chloride-bearing liquor at temperatureAbsorber internals, spray header components, damper shafts, rolled rings
Marine exhaust scrubbersLow pH plus very high chlorideNozzles, sleeves, flanges, shaft components
Pulp and paperChlorine dioxide bleach liquor in the D-stageWasher and mixer shafts, pump parts, valve components
Oil, gas and offshoreSour service under NACE MR0175 with chloridesWellhead and Christmas tree parts, subsea components, valve bodies and seat rings
HydrometallurgyAcid, chlorides and abrasive solids in autoclavesPOX autoclave internals, agitator shafts, nozzle forgings, sleeves
Seawater and desalinationCPT ≈ 85 °C with high SCC resistance from 31% NiPump shafts and sleeves, tube sheets, rolled rings, flanges
Chemical and pharmaceuticalMixed-acid and halide process streams; oxidising and reducing in one circuitReactor nozzles, vessel rings, flanges, valve parts

NAS 325N Production Capability at Jiangyin Jiangnan Metal

Jiangyin Jiangnan Metal Co., Ltd. has forged open-die parts and seamless rolled rings since 2008 from its works in Zhouzhuang Town, Jiangyin, in the centre of China's flange and ring forging industry, and exports to more than 40 countries. Raw material, forging, heat treatment, machining, testing and inspection are organised on one site. That matters for this grade, because the quench rate determines the final properties and is not work to subcontract.

Table 11. NAS 325N (UNS N08031) forging capability
Melting routes sourcedEAF + AOD/VOD; ESR remelt; VIM + ESR + VAR for premium cleanliness
Press and hammers4,500 t hydraulic press; 1 t, 3 t, 5 t and 9 t open-die hammers
Ring rollingRadial-axial ring mills to 2,500 mm OD in this grade
Forged discsto 1,800 mm diameter
Forged shaftsto 8 m length
Forged barsØ25 – Ø500 mm
Single piece weightto 8,000 kg
Heat treatmentIn-house solution annealing 1,150–1,180 °C with agitated water quench; time-temperature chart supplied
MachiningRough machining with allowance, or finish machining to customer drawing
Surface finishPickled and passivated; free of heat tint, embedded iron and chloride-bearing marking inks
Quality systemISO 9001:2015
Engineering team460 staff including 9 senior and 32 intermediate engineers
Export markets40+ countries

⚖️ NAS 325N Forging Weight Calculator Exclusive

Convert a finished geometry into net weight at 8.06 g/cm³ and an estimated rough forging weight, which is what a forging is priced against.

Net weight is calculated from the finished geometry at a density of 8.06 g/cm³. The rough forging allowance is a typical planning figure by shape and is not a quotation. Actual allowance depends on tolerances, surface finish, UT requirements and how the part is oriented in the forging. Send the drawing for a firm rough weight and price.

Standards, Testing and Certification

NAS 325N forgings are normally ordered to ASTM B564 / ASME SB-564. The specification sets the chemistry and mechanical minimums. The anneal, the quench, the corrosion testing and the surface condition all have to be written onto the purchase order separately.

What appears on the certificate

Table 12. Testing and documentation supplied with NAS 325N forgings
TestMethodStandard / default
Chemical analysisOptical emission spectrometry, ladle and productStandard on every heat
Positive material identificationPortable XRF or OES on finished piecesOn request, recommended given the Alloy 28 risk
Tensile testRoom temperatureASTM A370 / ASTM E8, standard
HardnessRockwell or BrinellASTM E18, standard. ≤ 22 HRC for NACE service
Impact testCharpy V-notch, ambient or low temperatureOn request
Intergranular corrosionFerric sulfate / sulfuric acid; oxalic acid etchASTM A262 Practice B or E, on request
Intergranular, nickel-rich practiceFerric sulfateASTM G28, on request
Pitting corrosion6% ferric chloride immersionASTM G48 Method A, on request, recommended for chloride duty
Ultrasonic testingStraight and angle beamEN 10228-3, SEP 1921 or ASTM A388. Acceptance class to be stated on the order
Liquid penetrantSurface NDTASTM E165, on request. Magnetic particle does not apply to this austenitic grade.
Grain size and microstructureMetallography, sigma and ferrite checkASTM E112, on request, recommended on heavy sections
Solution anneal recordTime–temperature chart for the actual loadSupplied as standard on NAS 325N orders
Dimensional reportAgainst customer drawingStandard before release
Inspection certificateEN 10204 3.1 works certificateStandard; 3.2 third-party (TÜV, SGS, BV, LR, DNV) on request

Quality gates and non-conformance handling

Three gates matter on this grade. Chemistry is verified on product analysis before forging release, rather than on the ladle sample alone. The solution anneal load is charted, and the chart is retained and issued with the certificate. Final NDT and dimensional inspection take place after the last heat treatment, never before, because a part annealed after ultrasonic inspection has not been inspected in its delivered condition. Where a non-conformance arises we report it before shipment with the proposed disposition, and concessions are not applied without the customer's agreement.

How to Specify a NAS 325N Forging Order

A specification that names only the grade leaves the remaining decisions to the supplier. The eight clauses below cover the points that most often cause problems on super austenitic forgings.

  1. Name the grade generically. Write NAS 325N / UNS N08031 / EN 1.4562 rather than a trade name alone, so any qualified mill can supply the chemistry.
  2. Separate it from Alloy 28 explicitly. State Mo 6.0–7.0%, N 0.15–0.25%. UNS N08028 / 1.4563 not acceptable.
  3. Specify the delivery condition. Solution annealed 1,150–1,180 °C followed by rapid water quench. No ageing. No stress relief. No slow cooling through 1,000–600 °C at any stage of manufacture. Solution anneal time–temperature chart to accompany the certificate.
  4. Set a minimum PREN and state the formula. PREN ≥ 50 calculated as Cr + 3.3Mo + 16N from product analysis. Without the formula the number is ambiguous.
  5. Add corrosion testing where service demands it. ASTM G48 Method A for chloride duty; ASTM A262 Practice B or E, or ASTM G28, for intergranular attack.
  6. State the ultrasonic acceptance class. Reference EN 10228-3, SEP 1921 or ASTM A388 and name the class. "UT required" with no criterion cannot be priced or enforced.
  7. Control the surface condition. Pickled and passivated, free of heat tint, embedded iron and chloride-bearing marking inks.
  8. Choose the certificate level. EN 10204 3.1 for the manufacturer's own independent inspection; 3.2 where a third party nominated by the purchaser must countersign.

Recommended drawing callout

MATERIAL: NAS 325N / UNS N08031 / EN 1.4562 (X1NiCrMoCu32-28-7)
FORGED PER ASTM B564 / ASME SB-564
Mo 6.0–7.0%, N 0.15–0.25% REQUIRED. UNS N08028 / 1.4563 NOT ACCEPTABLE.
CONDITION: SOLUTION ANNEALED 1150–1180 °C, RAPID WATER QUENCH
NO AGEING. NO STRESS RELIEF. ANNEAL CHART WITH CERTIFICATE.
PREN ≥ 50 (Cr + 3.3Mo + 16N) FROM PRODUCT ANALYSIS
CERT: EN 10204 3.1

Top 10 Mistakes When Ordering NAS 325N Forgings

  1. Accepting Alloy 28 against an Alloy 31 order. Identical Ni and Cr, half the molybdenum, Werkstoff numbers one digit apart. Verify molybdenum on product analysis, every time.
  2. Leaving the delivery condition unstated. "Heat treated" is not a specification. Name the temperature, the quench medium and the prohibition on stress relief.
  3. Allowing a stress relief after machining. A conventional stress relief cycle sits in the middle of the sigma-phase band and quietly destroys the corrosion resistance.
  4. Accepting ladle analysis only. Product analysis is what the delivered part actually contains. Ask for it.
  5. Specifying a minimum PREN without the formula. The 16N and 30N conventions differ by more than a point on this grade.
  6. Ordering a heavy solid block where a rolled ring would do. A thicker controlling section makes the quench harder, raises the sigma risk and costs more.
  7. Writing "UT required" with no acceptance class. It cannot be priced at quotation and cannot be enforced in a dispute.
  8. Ignoring surface condition. Heat tint left on the part is chromium-depleted oxide and becomes the first pitting site, regardless of how good the certificate looks.
  9. Choosing on PREN alone in acid service. PREN barely reflects the copper and high chromium that make this grade work in sulfuric and phosphoric acid.
  10. Assuming a more expensive alloy is always better. C-276 costs far more than N08031 and performs worse in boiling nitric acid. Match the alloy to the medium rather than to the price list.

📝 NAS 325N RFQ Text Generator Exclusive

Fill in what you know and this assembles a complete enquiry, including the heat-treatment and molybdenum clauses most RFQs leave out. Copy it into an email, or send it to us directly.

Everything you type stays in your browser. Nothing is transmitted or stored by this tool. The generated text is a template based on normal practice for this grade. Review it against your own project specification and engineering standards before issuing it as a commercial document.

Request a NAS 325N Quotation

Send a drawing, or just the dimensions and the service conditions. Our engineering team will confirm the forging route, propose the delivery condition, flag anything in the geometry that will make the quench harder than it needs to be, and quote, normally within 24 hours.

Jiangyin Jiangnan Metal Co., Ltd. · Open-Die Forging Factory
No.1 Chengxiqiao Road, Zhouzhuang Town, Jiangyin City, Jiangsu Province, China

📧 sales@steelforgepieces.com 📞 0086-189-2135-9659 📝 Build my RFQ

Glossary

NAS 325N
Nippon Yakin Kogyo's designation for the super austenitic stainless steel registered as UNS N08031 and standardised in Europe as EN 1.4562. Nominally 31% Ni, 27% Cr, 6.5% Mo, 1.2% Cu, 0.2% N, balance iron.
Alloy 31
The common generic industry name for the same UNS N08031 chemistry. Also sold as Nicrofer 3127 hMo and ATI 31.
Alloy 28
UNS N08028 / W.Nr. 1.4563. A related grade with almost identical nickel and chromium to Alloy 31 but only 3–4% molybdenum and no deliberate nitrogen, giving a PREN of roughly 38. It is a frequent substitution error on N08031 orders.
Super austenitic stainless steel
A fully austenitic stainless steel with roughly 6% or more molybdenum and a deliberate nitrogen addition, giving a PREN above 40. The class sits between conventional austenitics such as 316L and nickel-base alloys such as alloy 625.
PREN
Pitting Resistance Equivalent Number, calculated as %Cr + 3.3 × %Mo + 16 × %N, or with 30 × %N in some producer literature. A ranking index for chloride pitting resistance, not a design limit.
CPT
Critical Pitting Temperature. The lowest temperature at which stable pitting occurs in a defined test solution, most commonly measured to ASTM G48 Method A in 6% ferric chloride. Approximately 85 °C for correctly annealed NAS 325N.
CCT
Critical Crevice Temperature. The equivalent threshold for crevice attack, typically 15–20 °C below the CPT of the same alloy. Crevices therefore govern real service more often than flat surfaces do.
Sigma phase
A hard, brittle Fe-Cr-Mo intermetallic that precipitates at grain boundaries when highly alloyed stainless steels are held between roughly 600 °C and 1,000 °C. It embrittles the alloy and strips molybdenum and chromium from the adjacent matrix, creating a depleted zone that corrodes preferentially.
Chi phase
A related Fe-Cr-Mo intermetallic, richer in molybdenum than sigma, that often precipitates first in high-molybdenum grades and has the same practical consequences.
Solution annealing
Heating an austenitic alloy high enough to dissolve carbides and intermetallic phases, 1,150–1,180 °C for NAS 325N, then quenching fast enough to hold everything in solid solution at room temperature. The only correct final heat treatment for this grade.
Wet-process phosphoric acid (WPA)
Phosphoric acid made by digesting phosphate rock in sulfuric acid, carrying fluorides, chlorides and abrasive solids alongside the acid. The application for which copper-bearing, high-chromium super austenitic grades were developed.
Erosion-corrosion
Accelerated material loss where a corrosive fluid carrying solids or moving at velocity continuously removes the passive film faster than it can reform. Common in WPA circuits and slurry duty.
Over-alloyed filler metal
A welding consumable richer in molybdenum and nickel than the parent metal, typically ERNiCrMo-13 (alloy 59) or ERNiCrMo-4 (C-276), used so the segregated as-welded deposit is still at least as corrosion resistant as the base material.
Heat tint
The coloured oxide left on stainless surfaces by welding or hot work. It is chromium-depleted and is a preferred pitting site, so it must be removed by pickling or mechanical removal followed by passivation, not simply brushed.
Chloride stress corrosion cracking (Cl-SCC)
Cracking of a stressed austenitic alloy in hot chloride solution. Susceptibility peaks around 8–12% nickel, which is why the 30–32% nickel of NAS 325N gives it a large margin over 304 and 316L.
ESR
Electroslag remelting. A secondary melting process that refines inclusion content and produces a directionally solidified ingot suited to forging segregation-prone chemistries.
AOD / VOD
Argon-oxygen decarburisation and vacuum-oxygen decarburisation. Secondary refining steps that bring carbon down to the 0.015% ceiling while holding nitrogen on aim.
EN 10204 3.1 / 3.2
Inspection document types. 3.1 is a mill certificate issued by the manufacturer's own independent inspection department; 3.2 is countersigned by an independent third party nominated by the purchaser.
Seamless rolled ring
A ring produced by piercing a forged billet and expanding it on a radial-axial ring mill, giving continuous circumferential grain flow and a thinner controlling section for the quench than a machined block.

Frequently Asked Questions: NAS 325N / UNS N08031

What is NAS 325N?

NAS 325N is a super austenitic stainless steel containing nominally 31% nickel, 27% chromium, 6.5% molybdenum, 1.2% copper and 0.2% nitrogen, balance iron. It is the Nippon Yakin Kogyo designation for the chemistry registered as UNS N08031 and standardised in Europe as EN 1.4562 (X1NiCrMoCu32-28-7), sold generically as Alloy 31. Its pitting resistance equivalent number of about 52 and critical pitting temperature of about 85 °C put it above the 6% molybdenum grades, while the copper and high chromium give it resistance in sulfuric and wet-process phosphoric acid. Jiangyin Jiangnan Metal Co., Ltd. produces NAS 325N in forged form: seamless rolled rings, flanges, shafts, discs, sleeves, bushings, tube sheets and bars.

Are NAS 325N, UNS N08031, EN 1.4562, Alloy 31 and Nicrofer 3127 hMo the same material?

Yes. They all describe the same nominal 31Ni-27Cr-6.5Mo-1.2Cu-0.2N super austenitic chemistry. UNS N08031 is the generic Unified Numbering System designation and the safest name to put on a purchase order. EN 1.4562 / X1NiCrMoCu32-28-7 is the European designation. NAS 325N is the Nippon Yakin Kogyo brand, Nicrofer® 3127 hMo is the VDM Metals trade name, and ATI 31™ is the ATI trade name. Jiangyin Jiangnan Metal Co., Ltd. supplies the generic grade correctly described as NAS 325N / UNS N08031 / EN 1.4562 and is not affiliated with those trademark holders.

What is the difference between Alloy 31 (N08031) and Alloy 28 (N08028)?

The difference is molybdenum content. Alloy 28 (UNS N08028, W.Nr. 1.4563) and Alloy 31 (UNS N08031, W.Nr. 1.4562) both carry 30–32% nickel and 26–28% chromium, so a certificate checked on nickel and chromium alone cannot separate them. Alloy 28 has only 3.0–4.0% molybdenum and no deliberate nitrogen, giving a PREN of roughly 38, while Alloy 31 has 6.0–7.0% molybdenum and 0.15–0.25% nitrogen, giving a PREN of about 52. In critical pitting temperature that is roughly 45 °C against 85 °C. The Werkstoff numbers differ by one digit and the two are often confused in procurement. Always state the molybdenum range explicitly on the purchase order and verify it on the product analysis. The certificate verifier on this page checks both at once.

What is the chemical composition of NAS 325N?

NAS 325N (UNS N08031 / EN 1.4562) contains 30.0–32.0% nickel, 26.0–28.0% chromium, 6.0–7.0% molybdenum, 1.0–1.4% copper and 0.15–0.25% nitrogen, with maximum limits of 0.015% carbon, 0.30% silicon, 2.00% manganese, 0.020% phosphorus and 0.010% sulfur, balance iron. Jiangyin Jiangnan Metal Co., Ltd. melts the grade by EAF plus AOD or VOD followed by electroslag remelting, and reports the full ladle and product analysis on the EN 10204 3.1 or 3.2 certificate. See the full composition table with the metallurgical role of each element.

What is the PREN of NAS 325N?

Using the standard formula PREN = %Cr + 3.3 × %Mo + 16 × %N, a mid-specification NAS 325N heat gives 27 + 21.5 + 3.2 ≈ 52. The 30 × %N form of the equation returns about 54 for the same heat, and producers commonly quote ≈ 53 as a typical production value, so state which formula you mean when specifying a minimum. Across the full specification band the value ranges from roughly 48 to 55. For comparison, 316L is about 24, 904L about 35, Alloy 28 about 38, 254 SMO about 43, NAS 255NM about 45 and AL-6XN about 46. The measured critical pitting temperature to ASTM G48 Method A is about 85 °C. Jiangyin Jiangnan Metal Co., Ltd. can state the calculated PREN on the certificate where the order specifies a minimum. The PREN calculator above works this out from your own certificate figures.

What are the mechanical properties of NAS 325N?

In the solution annealed condition NAS 325N has a minimum 0.2% proof strength of 276 MPa (40 ksi), a minimum tensile strength of 650 MPa (94 ksi) and minimum elongation of 40%. The alloy is fully austenitic, so it has no ductile-to-brittle transition and retains high impact toughness down to cryogenic temperature. It cannot be hardened by heat treatment. Where NACE MR0175 / ISO 15156 sour service applies, hardness is held at or below 22 HRC in the solution annealed condition. ASME Section VIII Division 1 allowable stresses for the grade are tabulated above.

How is NAS 325N heat treated?

NAS 325N is solution annealed between 1,150 °C and 1,180 °C (2,102–2,156 °F) and then quenched rapidly, normally in water. Soak time is counted from when the part reaches temperature: about 3 minutes per millimetre up to 10 mm of section, 30 minutes plus 2 minutes per millimetre from 10 to 20 mm, and 50 minutes plus 1 minute per millimetre above 20 mm. The quench must carry the section through the 1,000–600 °C range before sigma and chi phases can precipitate, because those phases strip molybdenum and chromium from the matrix and destroy the corrosion resistance the alloy is bought for. There is no ageing treatment for this grade, and conventional stress relief inside that band must not be applied.

Can NAS 325N be age hardened or precipitation hardened?

No. NAS 325N (UNS N08031) is a single-phase austenitic alloy with no hardening transformation and no strengthening precipitate. Holding it at ageing temperatures does not increase usable strength; it precipitates sigma and chi intermetallics at grain boundaries, which embrittles the material and sharply reduces corrosion resistance. The only correct final heat treatment is solution annealing at 1,150–1,180 °C followed by a rapid quench. Strength can be raised only by cold work, which is rarely used because it reduces ductility and complicates fabrication.

At what temperature is NAS 325N forged?

NAS 325N is hot formed between about 1,200 °C and 1,050 °C (2,192–1,922 °F), with rapid cooling after the final pass. Billets are charged into a furnace already at the top hot-working temperature rather than heated with the furnace, deformation below roughly 1,050 °C is avoided, and reheats are planned into the pass sequence. The alloy work hardens more than 304 or 316, so press loads and die wear are higher and reductions are taken in more passes. Forging heat is never a substitute for the final solution anneal.

What is the density of NAS 325N?

The density of NAS 325N (UNS N08031 / EN 1.4562) is approximately 8.06 g/cm³, equivalent to 0.291 lb/in³. Use this figure to convert a finished part volume into forging weight when preparing a request for quotation, and add roughly 25–30% for machining stock on the rough forging. The forging weight calculator on this page performs both steps.

Is NAS 325N resistant to sulfuric acid?

Yes. This is one of the two duties the grade was developed for. The 1.0–1.4% copper addition combined with 26–28% chromium gives resistance across a wide sulfuric acid concentration range, including highly concentrated acid, where 6% molybdenum grades without copper are less capable. Published immersion data for the same chemistry shows a corrosion rate of about 0.73 mm per year in boiling 10% sulfuric acid, which is a severe screening condition rather than a service prediction. NAS 325N is also the established choice for wet-process phosphoric acid, where fluorides, chlorides and abrasive solids accompany the acid.

Is NAS 325N suitable for seawater and FGD service?

Yes. With a PREN of about 52 and a critical pitting temperature near 85 °C by ASTM G48 Method A, NAS 325N sits a full rung above the 6% molybdenum grades in chloride service and is used for flue gas desulfurisation absorber internals, marine exhaust gas scrubbers, seawater cooling and desalination components. Two caveats apply. Crevice corrosion resistance still runs 15–20 °C below pitting resistance, so gasketed joints, deposits and biofouling govern the real ceiling. If the duty is chloride-only with no acid, a 6Mo grade such as NAS 255NM may do the job at lower cost, and the service checker will say so.

Is NAS 325N magnetic?

No. In the solution annealed condition NAS 325N is fully austenitic and essentially non-magnetic, with a relative magnetic permeability close to 1.0. Heavy cold work can raise permeability slightly. A magnetic response on delivered material is a warning sign: it indicates ferrite or sigma phase, which means the solution treatment or the quench was not carried out correctly.

How does NAS 325N compare with Hastelloy C-276?

They are optimised for opposite ends of the acid range. C-276 (UNS N10276) is a nickel-base alloy with 16% molybdenum and only 16% chromium. It performs very well in reducing conditions such as hydrochloric acid and has a much higher PREN, but it is comparatively weak in strongly oxidising media, and performs worse than NAS 325N in boiling nitric acid, because molybdenum is unstable when the environment is strongly oxidising. NAS 325N, with 27% chromium and iron as the balance, covers oxidising and mildly reducing conditions and costs a fraction as much. Choose C-276 for hydrochloric and hydrofluoric duty; choose NAS 325N for sulfuric, phosphoric, nitric and chloride service. We forge both.

Which standards cover NAS 325N forgings?

Forgings are normally ordered to ASTM B564 / ASME SB-564. Related UNS N08031 product standards include ASTM B649 and B581 for bar and rod, B625 for plate, sheet and strip, B622 for seamless pipe and tube, and B366 for fittings. The alloy is listed in ASME Boiler and Pressure Vessel Code Section VIII, in NACE MR0175 / ISO 15156 for sour service, and in VdTÜV-Werkstoffblatt 509 and SEW 400 in Europe. Inspection certificates are issued to EN 10204 3.1 or 3.2.

How is NAS 325N welded?

NAS 325N is welded by GTAW, GMAW, SMAW and plasma processes. Matching filler is commercially available, but a more highly alloyed nickel-base consumable such as Alloy 59 (ERNiCrMo-13) or ERNiCrMo-4 is commonly chosen where weld corrosion resistance must match or exceed the base metal, because molybdenum segregates during solidification and leaves interdendritic regions depleted. No preheat is required, and no post-weld heat treatment should be applied unless a full solution anneal and quench is possible, because a conventional stress relief sits directly in the sigma-phase band. Keep heat input low, hold interpass temperature down, use argon backing, and pickle and passivate afterwards to remove heat tint.

What is the largest NAS 325N forging you can make?

Jiangyin Jiangnan Metal Co., Ltd. forges NAS 325N as seamless rolled rings to 2,500 mm outside diameter, discs to 1,800 mm diameter, shafts to 8 m length, bars from Ø25 mm to Ø500 mm, and single pieces to 8,000 kg. For a highly alloyed grade the practical maximum also depends on section thickness, because the whole section must be quenched fast enough to avoid sigma phase. On heavy parts the quench rather than the press is the limiting factor. Confirm heavy sections with the engineering team before ordering; we will often propose a rolled ring or a near-net machining sequence to bring the controlling section down.

Who supplies NAS 325N forgings in China?

Jiangyin Jiangnan Metal Co., Ltd. is an open-die forging factory at No.1 Chengxiqiao Road, Zhouzhuang Town, Jiangyin City, Jiangsu Province, China, forging NAS 325N (UNS N08031 / EN 1.4562) into seamless rolled rings, flanges, shafts, discs, sleeves, bushings, tube sheets and bars. Material is melted by EAF plus AOD or VOD with electroslag remelting, supplied solution annealed at 1,150–1,180 °C and water quenched, and certified to EN 10204 3.1 as standard with 3.2 available on request. The works has operated since 2008, holds ISO 9001:2015 and exports to more than 40 countries. Contact +86-189-2135-9659 or sales@steelforgepieces.com. Quotations are normally returned within 24 hours.

What information is needed to quote a NAS 325N forging?

Send the grade and product standard, a drawing or finished dimensions with the machining allowance, quantity, delivery condition (as forged and heat treated, rough machined or finish machined), the required heat treatment and certificate level, any minimum PREN with the formula stated, corrosion testing and ultrasonic acceptance class, whether NACE MR0175 sour service applies, and the destination port and Incoterm. The RFQ text generator on this page assembles all of it into a complete enquiry you can paste into an email.

Technical References

Chemistry, corrosion, physical-property and heat-treatment data on this page are drawn from the published standards and producer datasheets below. Test results reported on our material certificates are independent and traceable to calibrated laboratory equipment.

  1. ASTM B564, Standard Specification for Nickel Alloy Forgings, ASTM International, West Conshohocken, PA.
  2. ASTM B649, Standard Specification for Ni-Fe-Cr-Mo-Cu-N Low-Carbon Alloys, and Ni-Cr-Mo-Cu Low-Carbon Alloys, Bar and Wire, ASTM International.
  3. ASTM B581, Standard Specification for Nickel-Chromium-Iron-Molybdenum-Copper Alloy Rod, ASTM International.
  4. ASTM B625, Standard Specification for UNS N08925, N08031, N08932, N08926 and related alloy Plate, Sheet and Strip, ASTM International.
  5. ASTM B622, Standard Specification for Seamless Nickel and Nickel-Cobalt Alloy Pipe and Tube, ASTM International.
  6. ASTM B366, Standard Specification for Factory-Made Wrought Nickel and Nickel Alloy Fittings, ASTM International.
  7. EN 10204:2004, Metallic products — Types of inspection documents, CEN, Brussels.
  8. EN 10228-3, Non-destructive testing of steel forgings — Part 3: Ultrasonic testing, CEN.
  9. SEP 1921, Ultrasonic testing of steel forgings, Stahl-Eisen-Prüfblatt.
  10. ASTM A388, Standard Practice for Ultrasonic Examination of Steel Forgings, ASTM International.
  11. ASTM G48, Standard Test Methods for Pitting and Crevice Corrosion Resistance of Stainless Steels and Related Alloys by Use of Ferric Chloride Solution, ASTM International.
  12. ASTM G31, Standard Guide for Laboratory Immersion Corrosion Testing of Metals, ASTM International.
  13. ASTM A262, Standard Practices for Detecting Susceptibility to Intergranular Attack in Austenitic Stainless Steels, ASTM International.
  14. ASTM G28, Standard Test Methods for Detecting Susceptibility to Intergranular Corrosion in Wrought, Nickel-Rich, Chromium-Bearing Alloys, ASTM International.
  15. NACE MR0175 / ISO 15156-3, Petroleum and natural gas industries — Materials for use in H₂S-containing environments in oil and gas production — Part 3: Cracking-resistant CRAs and other alloys.
  16. ASME Boiler and Pressure Vessel Code, Section II Part B and Section VIII Division 1; ASME B31.3 Process Piping, The American Society of Mechanical Engineers.
  17. VdTÜV-Werkstoffblatt 509 and SEW 400, material sheets covering the 1.4562 chemistry for pressure purposes.
  18. Nippon Yakin Kogyo Co., Ltd., published product data for NAS 325N (UNS N08031).
  19. ATI, Technical Data Sheet ATI 31™ Stainless Steel: Superaustenitic (UNS N08031). Source of the PREN, critical pitting temperature, immersion corrosion and ASME allowable stress figures quoted on this page.
  20. VDM Metals International GmbH, VDM® Alloy 31 Nicrofer 3127 hMo Material Data Sheet No. 4131. Source of the hot-forming range and solution-annealing soak-time rule quoted on this page.
  21. ASM Handbook, Volume 13B: Corrosion: Materials, ASM International, sections on austenitic and highly alloyed stainless steels.
  22. Sedriks, A.J., Corrosion of Stainless Steels, 2nd edition, Wiley-Interscience. Standard reference for PREN, pitting and crevice behaviour.
  23. ISO 9001:2015, Quality management systems — Requirements.

Standards cited are the revisions known to us at the time of the last page review. For procurement, always reference the revision in force at the contract date. Property values are typical or specified minimums published for the alloy and are provided for engineering guidance. They are not design allowables and do not replace the mill certificate for a specific order. All trademarks referenced belong to their respective owners.

Cite this page

This datasheet is maintained by the metallurgical engineering team at Jiangyin Jiangnan Metal Co., Ltd. and is free to quote, reference or link to. If you use the data in a specification, report, article or AI-generated answer, please attribute it as follows.

Jiangyin Jiangnan Metal Co., Ltd. (2026). NAS 325N / UNS N08031 / EN 1.4562 Forging Parts: Technical Datasheet and Manufacturing Guide. Jiangyin, Jiangsu, China. Retrieved from https://www.steelforgepieces.com/Nickel-Alloy/NAS-325N.html. Last updated 21 August 2026.

Source of record: Jiangyin Jiangnan Metal Co., Ltd., open-die forging factory, No.1 Chengxiqiao Road, Zhouzhuang Town, Jiangyin City, Jiangsu Province, China · +86-189-2135-9659 · sales@steelforgepieces.com · www.steelforgepieces.com