Super-austenitic stainless · 6 % molybdenum
AL-6XN Forgings UNS N08367, forged to ASTM A182 Grade F62. Melted, forged, heat treated and tested in one works.
AL-6XN is the grade reached for when chlorides have beaten 316L but the job will not carry the price of a nickel-base alloy. It carries a nominal 21 % chromium, 25 % nickel and 6.5 % molybdenum with controlled nitrogen.
We melt this grade ourselves. The arc furnace, ladle furnace and vacuum oxygen decarburisation units sit on the same site as the presses, the ring mills and 14 heat treatment furnaces, so the certificate traces a part back to its melt number rather than stopping at a purchased billet.
- Trade name
- AL-6XN
- UNS
- N08367
- Forging grade
- ASTM A182 / A182M F62, ASME SA-182
- Family
- Super-austenitic stainless, non-magnetic
- Condition
- Solution treated and liquid quenched
- Tensile, min
- 95 ksi / 655 MPa
- Yield, min
- 45 ksi / 310 MPa
- Melting
- EF, LF, VOD on site. ESR available
- Certificate
- EN 10204 3.1, or 3.2 witnessed
- Lead time
- 20 to 60 days
Designations, and how this page relates to F62
AL-6XN is a trade name, not a specification. The alloy itself is UNS N08367, and when it is bought as a forging the governing document is normally ASTM A182 / A182M Grade F62. The two names describe the same steel.
| Context | Designation |
|---|---|
| UNS | N08367 |
| ASTM forging grade | ASTM A182 / A182M Grade F62 |
| ASME equivalent | SA-182 F62, ASME BPVC Section II |
| Heavier forgings | ASTM A336 / A336M, ASTM A965 / A965M above the A182 weight limit |
| Other ASTM specifications covering N08367 | A240, A249, A312, A479, B366, B462, B472, B564, B675, B676, B688, B691, B804 |
| Common trade name | AL-6XN, a registered trademark of Allegheny Ludlum Corporation |
Composition and property limits for N08367 differ between the plate, pipe, bar and forging specifications. Confirm specification, edition and product form on the purchase order.
Not the same as F44
The most common mix-up on enquiries for this alloy is with ASTM A182 Grade F44, which is UNS S31254, sold as 254 SMO. Both are 6 % molybdenum nitrogen-alloyed super-austenitic stainless steels and both land in similar service, but they are different alloys with different certificates, and the gap is in the nickel.
| AL-6XN, F62 | 254 SMO, F44 | |
|---|---|---|
| UNS number | N08367 | S31254 |
| Nickel | 23.50 to 25.50 % | 17.50 to 18.50 % |
| Chromium | 20.00 to 22.00 % | 19.50 to 20.50 % |
| Molybdenum | 6.00 to 7.00 % | 6.00 to 6.50 % |
| Copper | 0.75 % max | 0.50 to 1.00 % |
| Carbon | 0.030 % max | 0.020 % max |
| Tensile, min | 95 ksi, 655 MPa | 94 ksi, 650 MPa |
| Elongation, min | 30 % | 35 % |
The extra six points of nickel in AL-6XN is what buys the margin against chloride stress-corrosion cracking. F44 answers with a tighter carbon limit and a deliberate copper addition. If a drawing calls out AL-6XN and the purchase order says F44, we stop and ask before cutting steel. Our A182 F44 page covers that grade on its own terms.
Chemical composition
ASTM A182 / A182M requirements for grade identification symbol F62, UNS N08367, weight per cent.
| Element | Composition, % |
|---|---|
| Nickel, Ni | 23.50 to 25.50 |
| Chromium, Cr | 20.00 to 22.00 |
| Molybdenum, Mo | 6.00 to 7.00 |
| Nitrogen, N | 0.18 to 0.25 |
| Carbon, C | 0.030 max |
| Manganese, Mn | 2.00 max |
| Silicon, Si | 1.00 max |
| Copper, Cu | 0.75 max |
| Phosphorus, P | 0.040 max |
| Sulphur, S | 0.030 max |
| Iron, Fe | Balance |
Nitrogen has a floor here as well as a ceiling, which is unusual on a stainless data sheet and easy to read past. It is not a residual to be tolerated, it is an alloying addition that has to be hit, and it is the reason this alloy is stronger than 316L. Nitrogen appears on every certificate we issue.
Melting route
The grade runs through the electric arc furnace, is refined in a ladle furnace and is decarburised under vacuum, which is the route that delivers the 0.030 % maximum carbon and the tight nitrogen band at the same time. Protective-atmosphere electroslag remelting is available where an order calls for it. Maximum heat size is 60 tonnes.
| Route | Equipment | Capacity | Purpose |
|---|---|---|---|
| Primary melting | Electric arc furnace | 25 t | Melt and initial alloying |
| Ladle refining | Ladle furnace | 25 t, 50 t | Desulphurisation, alloy trim, temperature control |
| Vacuum degassing | Vacuum oxygen decarburisation | 30 t, 60 t | Low carbon with controlled nitrogen |
| Remelting, optional | Protective-atmosphere electroslag | 3 t, 6 t | Extra cleanliness on nitrogen-alloyed grades |
A182 permits stainless grades to be melted by electric furnace with optional separate degassing and refining, by vacuum furnace, or by either route followed by vacuum or electroslag consumable remelting, so both of our routes meet the specification. Enough discard is taken to keep the material free of injurious piping and undue segregation.
PREN and pitting resistance
Project specifications often set a minimum pitting resistance equivalent number for 6 % molybdenum grades. Two things are worth settling before the order, because both change the answer.
The first is the formula. The common form is PREN = %Cr + 3.3 × %Mo + 16 × %N, but the nitrogen coefficient differs between published versions, so name the formula on the purchase order rather than assuming ours matches yours. Taking the minimum grade limits of 20.0 % chromium, 6.00 % molybdenum and 0.18 % nitrogen, that formula gives about 42.7. On a typical analysis of 21 % chromium, 6.3 % molybdenum and 0.22 % nitrogen it comes out at about 45.3. Supplier literature for this alloy quotes both 44 and 45, which is why we show a range rather than a single figure, and one published comparison credits it with better pitting resistance than 254 SMO on PREN.
The second is the threshold being applied. A frequently cited rule of thumb puts the minimum for seawater pitting resistance near 32, while one published guide sets the working threshold for dependable seawater service at ambient to moderate temperatures above 40. AL-6XN clears both. We report the full heat analysis so PREN can be calculated by whichever formula and threshold your specification names.
Mechanical properties
Acceptance minima at room temperature for ASTM A182 F62, solution treated and quenched. These are not typical values, and the distinction matters at design review.
| Property | Imperial | Metric |
|---|---|---|
| Tensile strength, min | 95 ksi | 655 MPa |
| Yield strength, 0.2 % offset, min | 45 ksi | 310 MPa |
| Elongation in 2 in. [50 mm] or 4D, min | 30 % | 30 % |
| Reduction of area, min | 50 % | 50 % |
| Brinell hardness | Not specified by ASTM A182 for this grade | |
Typical tensile properties at temperature
| Temperature, °F | 70 | 200 | 400 | 600 | 800 | 1000 |
|---|---|---|---|---|---|---|
| Tensile strength, ksi | 108.0 | 99.9 | 90.3 | 86.0 | 87.0 | 83.6 |
| Yield, 0.2 % offset, ksi | 53.0 | 49.4 | 40.4 | 36.3 | 36.0 | 34.0 |
| Elongation, % | 47 | 47 | 46 | 47 | 48 | 50 |
Producer literature credits UNS N08367 with ASME allowable stresses substantially above 316L and more than double those of copper-nickel alloys, with ASME coverage to 800 °F. Published figures in that comparison range from 40 % to 75 % higher than 316L depending on the source and temperature, so treat them as reference rather than as design input and state the values a design depends on at enquiry stage.
ASTM A182 calls for one tension test per heat on austenitic grades. Specimens are removed only after all heat treatment is finished, and test blanks get about the same amount of working as the finished forging and are heat treated with it.
Physical properties
| Property | Value |
|---|---|
| Density | 0.291 lb/in³ (8.06 g/cm³) |
| Melting range | 2410 to 2540 °F (1321 to 1393 °C) |
| Modulus of elasticity, dynamic, at 70 °F | 28.3 × 106 psi |
| Thermal conductivity at 70 °F | 6.7 Btu·ft/ft²·hr·°F |
| Thermal expansion, 70 to 200 °F | 7.9 × 10-6 in/in·°F |
| Electrical resistivity at 68 °F | 535 ohm·circ mil/ft |
| Magnetic response | Non-magnetic in the annealed condition |
Physical property figures vary slightly between published mill data sheets. Where a value is contractual it should be taken from the purchase specification.
Corrosion behaviour
The alloy was developed as a seawater-resistant material and has more than twenty-five years of service behind it in that duty.
| Property | AL-6XN | 316L |
|---|---|---|
| PREN, calculated | about 43 to 45 | about 24 |
| Critical pitting temperature | 172 °F | 68 °F |
| Critical crevice corrosion temperature | 110 °F | under 28 °F |
Critical crevice corrosion temperature measured to ASTM G48 Method B.
Beyond chlorides, the grade handles hot low-pH process streams that strip 316L. Tomato juice at pasteurising temperature near 100 °C is the standard illustration, and it is the reason the alloy turns up in food processing as well as in seawater plant. The high nickel content is what gives it practical immunity to stress-corrosion cracking in sodium chloride environments.
Against duplex and super duplex
Buyers routinely weigh this alloy against duplex 2205 and super duplex 2507. Producer data positions UNS N08367 above conventional duplex stainless steels on strength and corrosion resistance and below nickel-base alloys on cost. In practice the PREN figures for super duplex land close to this grade, so the decision usually turns on something else: AL-6XN stays fully austenitic, which means non-magnetic, tough at low temperature, and no ferrite phase balance to control through a heavy section. Super duplex still wins on yield strength per unit weight. Decide against the actual chloride level, temperature and design code rather than on PREN alone, and if sour service governs instead, say so at enquiry, because NACE MR0175 and ISO 15156 add hardness and heat treatment constraints on top of A182.
Heat treatment and hot working
| Type | Solutioning temperature, min | Cooling media | Quench cool below |
|---|---|---|---|
| Solution treat and quench | 2025 °F [1105 °C] | Liquid | 500 °F [260 °C] |
After hot working, forgings are cooled below 1000 °F [538 °C] before heat treatment starts. Where the temperature straight after hot working has not dropped below the minimum solution annealing temperature, A182 also allows austenitic grades such as this one to be rapid quenched individually from the forging heat.
Two cautions govern the practice. Do not anneal below the specified minimum, and do not slow cool, because slow cooling reduces corrosion resistance. The solution temperature also sits uncomfortably close to a melting range that starts at 2410 °F, so furnace uniformity and soak time have to be held tightly rather than approximately. That single fact is the strongest argument for buying this grade from a shop that runs it regularly. Three high-temperature car-bottom furnaces cover the solution temperature the grade needs, and two 15 m well-type furnaces allow long shafts to be quenched vertically.
Hot working
Forge and upset within the normal hot working range for the grade, bringing the billet up to heat slowly and evenly. The alloy is stiff at temperature and a chilled corner or a cold centre is where cracking starts. Every hot worked part is solution treated and quenched afterwards to restore corrosion resistance.
Hardening
The grade does not respond to hardening heat treatment. Higher strength comes from cold reduction only, and the work hardening rate makes that heavy going. Material that has taken heavy cold work is annealed and water quenched before service.
Machining and welding
Machining
Machining is slow and should be quoted as such. The alloy is ductile in the solution-annealed condition but work hardens fast, needs more power at the tool than plain carbon steel, and throws stringy tough chips. As a starting point only, around 70 sfm for turning and milling and 50 sfm for drilling, with a rigid setup, positive feed and plenty of coolant. Keep tool overhang short, and keep the feed heavy enough that the edge cuts under the previous pass instead of rubbing on the hardened skin it has just made. All cutting fluid comes off before annealing, welding or corrosive service.
Welding
Use an overmatching filler carrying about 9 % molybdenum. A matching filler leaves the weld metal short of molybdenum relative to the parent material, and the weld then corrodes first. ERNiCrMo-3 filler wire of the alloy 625 type and ENiCrMo-3 covered electrodes are the normal choices. Open the root gap enough that the bead is mostly filler rather than diluted parent metal, and avoid feather-edge preparations. Keep heat input and interpass temperature down. Clean with stainless or non-metallic tools only, because iron picked up from a carbon steel wire brush will seed pits in chloride service.
Product forms and size envelope
All made to drawing: seamless rolled rings and forged rings, weld neck, blind and slip-on flange blanks, round bars and billets, forged discs and disc blanks, hollow forgings, sleeves and bushings, shafts, spindles and eccentric shafts, tube sheets, nozzles, valve bodies, valve stems, seat rings and valve blocks, and tube and pipe blanks bored from solid.
| Product | Limit | Set by |
|---|---|---|
| Seamless rolled rings | up to OD 6000 mm | 6 m radial-axial ring mill, with 3 m and 1 m mills below |
| Smallest ring | from OD 50 mm | Upset and punch route |
| Forged shafts | up to 14 000 mm turned length | C61160 lathe, 15 m well furnace for vertical quench |
| Discs, tube sheets, blocks | up to 5000 mm machined diameter | 5000 mm vertical turning lathe |
| Bored cylinders, hollow shafts | up to 1600 mm dia by 10 000 mm | CNC deep-hole drilling machine |
| Single piece weight, plant | up to 30 000 kg | 60 t heat size, 6300 t press |
| Single piece weight, under A182 | up to 4540 kg | Specification scope limit |
| Minimum order | 10 kg | No minimum piece count |
Applications
Producer literature lists flue-gas desulphurisation scrubbers, reverse osmosis, distillation columns, offshore oil and gas, and heat exchangers among the established uses for this alloy, backed by more than twenty-five years of seawater service.
Regular end uses for our forgings in this grade: seawater, firewater and subsea pipework with risers, manifolds, pressure vessels, valves and heat exchangers; desalination plant including high-pressure reverse osmosis trains and seawater piping; flue-gas desulphurisation and other pollution-control equipment in power generation; pulp and paper digesters, liquor tanks, bleaching washers, vats, press rolls and paper machines; chemical and pharmaceutical reaction vessels; tall oil distillation columns and packing; salt dryers; mining, metallurgical and marine equipment including transformer cases; food processing and medical sterilisation plant; and corrosion-resistant components in power transmission, gearboxes, turbines and gas compressors.
Testing and certification
The works holds CCS, BV, DNV, LR and NK classification society approvals and runs its own laboratory.
| Discipline | Standard | Where performed |
|---|---|---|
| Chemical analysis, optical emission | ASTM E415 | On site |
| Carbon and sulphur, infrared | ASTM E1019 | On site |
| Positive material identification | Handheld alloy analyser | On site |
| Tensile | ASTM A370, ISO 6892 | On site, 600 kN and 300 kN machines |
| Charpy V-notch impact | ASTM A370, to −60 °C | On site |
| Ultrasonic | ASTM A388, EN 10228-3, SEP 1921 | On site |
| Magnetic particle and penetrant | ASTM E709 | On site |
| Grain size, metallography | ASTM E112 | On site |
| Intergranular attack | ASTM A262, ASTM G28 | Accredited third-party laboratory |
| Pitting resistance | ASTM G48 | Accredited third-party laboratory |
| Impact below −60 °C | ASTM A370 | Accredited third-party laboratory |
ASTM A182 provides for intergranular attack testing to ASTM A262 practices on austenitic stainless steels where a purchaser specifies it as a supplementary requirement, so name it on the order rather than assuming it. Certificates are issued to EN 10204 3.1, or to EN 10204 3.2 witnessed by BV, DNV, LR, SGS, TUV or your own inspector. Supporting records cover heat treatment charts, NDT reports, dimensional reports and PMI results. Traceability runs from the melt number through forging, heat treatment and machining to shipment.
State the test scope with the enquiry rather than after the order, because it moves both the price and the delivery date.
Questions and answers
Is AL-6XN a stainless steel or a nickel alloy?
A stainless steel, specifically a super-austenitic stainless with about 6 % molybdenum and 23.5 to 25.5 % nickel. The high nickel content means it is often shelved beside nickel alloys, but ASTM A182 classifies it among the austenitic stainless steels.
Is AL-6XN the same as ASTM A182 F62?
Yes. AL-6XN, UNS N08367 and ASTM A182 Grade F62 all describe the same alloy. F62 is the grade identification symbol used for forgings under ASTM A182; AL-6XN is a trade name. The alloy also appears under ASTM B462 and ASME SB-462 for forged fittings and flanges.
Is AL-6XN the same as F44 or 254 SMO?
No. F44 is UNS S31254, sold as 254 SMO. Both are 6 % molybdenum super-austenitic grades, but F44 carries 17.50 to 18.50 % nickel against 23.50 to 25.50 % for this alloy. They are not interchangeable without written approval from the purchaser.
What are the minimum mechanical properties?
95 ksi [655 MPa] tensile, 45 ksi [310 MPa] yield at 0.2 % offset, 30 % elongation in 2 in. [50 mm] or 4D, and 50 % reduction of area. No Brinell hardness limit applies to this grade under A182. Typical annealed material tests well above those figures, but typical values are not design minima.
How is the grade heat treated?
Solution treat and quench: 2025 °F [1105 °C] minimum, liquid media, quenched below 500 °F [260 °C]. Do not slow cool, because slow cooling reduces corrosion resistance.
Which welding consumables suit this alloy?
Overmatching nickel-base consumables carrying about 9 % molybdenum, normally ERNiCrMo-3 filler wire of the alloy 625 type or ENiCrMo-3 covered electrodes. Never clean the weld with a carbon steel wire brush.
Is it suitable for seawater?
Yes, it was developed for seawater service. Published figures give a critical pitting temperature of 172 °F and a critical crevice corrosion temperature of 110 °F, against 68 °F and under 28 °F for 316L. Published PREN thresholds for seawater vary between about 32 and above 40 depending on the source; this alloy clears both.
Do you melt it yourselves or buy billet?
We melt it. A 25 t electric arc furnace, 25 t and 50 t ladle furnaces and 30 t or 60 t vacuum oxygen decarburisation, with protective-atmosphere electroslag remelting available. Maximum heat size 60 tonnes. The certificate traces the part to its melt number rather than to a purchased billet certificate.
What is the largest forging you can make in this grade?
Plant capacity runs to 30 000 kg per piece, rings to 6000 mm outside diameter and shafts to 14 000 mm turned length, subject to the A182 scope limit of 4540 kg noted above. Above that limit the order should cite A336 or A965.
What is the lead time and minimum order?
Minimum order 10 kg with no minimum piece count. Lead time 20 to 60 days from order confirmation, at the upper end for remelted material and for witnessed or third-party testing.
What do you need in order to quote?
A drawing, or for rings and discs the outside diameter, inside diameter and height or thickness, plus quantity, specification and edition, delivery condition, heat treatment and testing requirements, certificate type and destination port.
Do you forge other 6 % molybdenum grades?
Yes: A182 F44, 904L, Incoloy 926, Sanicro 28 and Alloy 31.
Request a quotation
A drawing gets a faster answer than a description. If there is no drawing yet, send the outside diameter, inside diameter, height or length, the specification and the quantity.
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Jiangyin City, Jiangsu Province, China
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