UNS N07725 / Alloy 725 / W.Nr. 2.4667
UNS N07725 Forgings
Open-die forged rings, flanges, bars, discs, sleeves and shafts in age-hardenable Ni-Cr-Mo-Nb alloy 725 for sour service, subsea and seawater duty.
UNS N07725, also known as Alloy 725, is an age-hardenable nickel-chromium-molybdenum-niobium alloy. It has essentially the same corrosion resistance as alloy 625, with about twice the strength of alloy 625 in the annealed condition. Strength is developed by solution annealing and a two-stage ageing treatment instead of by cold work, so heavy and non-uniform forged sections reach full properties while keeping high ductility and toughness. The alloy is listed in NACE MR0175 / ISO 15156-3 for sour oil and gas service.
Jiangyin Jiangnan Metal Co., Ltd. is an open-die forging factory in Jiangyin, Jiangsu Province, China. We forge UNS N07725 to customer drawing in the form of seamless rolled rings, flanges, round bars, discs, tube sheets, sleeves, bushings and shafts. Forgings are supplied solution annealed and aged, 100% ultrasonically tested, with EN 10204 3.1 or 3.2 certification. Send a drawing to sales@steelforgepieces.com or call 0086-189-2135-9659.
- Alloy type
- Ni-Cr-Mo-NbAge hardenable, gamma double prime
- Nickel
- 55.0 to 59.0 %Cr 19.0 to 22.5, Mo 7.0 to 9.5
- Tensile strength
- 1035 MPa min150 ksi, aged condition
- Yield 0.2 %
- 827 MPa min120 ksi, aged condition
- Hardness limit
- 43 HRC maxNACE MR0175 sour service
- Density
- 8.31 g/cm³Melting range 1271 to 1343 °C
Metallurgy
What UNS N07725 is
UNS N07725 is a nickel base superalloy containing nominally 57% nickel, 21% chromium, 8% molybdenum and 3.4% niobium, with a titanium addition of 1.0 to 1.7%. The high nickel and chromium content gives corrosion resistance in both reducing and oxidising environments. The molybdenum content gives resistance to reducing media and a high degree of resistance to pitting and crevice corrosion. The combination of these elements also makes the alloy resistant to hydrogen embrittlement and stress-corrosion cracking.
Strength is developed by precipitation of the gamma double prime phase (Ni3Nb) during ageing. This is the same strengthening mechanism used in alloy 718, but N07725 carries higher chromium and molybdenum and much lower aluminium, so it retains the corrosion resistance of alloy 625 while reaching roughly twice the strength of annealed 625. Because the strength does not come from cold work, a heavy forged block develops the same properties as a small diameter bar.
Alloy 725 is normally specified where a part must carry high load and also resist hydrogen sulphide, carbon dioxide, chlorides and elemental sulphur at temperature. Common applications are hangers, landing nipples, side pocket mandrels and polished bore receptacles in sour gas wells, and high strength fasteners in seawater service.
Reference
Designations and standards
| UNS number | N07725 |
|---|---|
| Common names | Alloy 725, Inconel 725, Nickelvac 725, Nicrofer 5621 |
| Werkstoff Nr. | 2.4667 |
| Bar and wire | ASTM B805 |
| Bar and forging stock | SMC HA91, ASME Code Case 2217 |
| Forgings | ASTM B564 practice for nickel alloy forgings, or to end user specification. Grade coverage varies by edition, so the applicable revision is confirmed at enquiry. |
| Sour service | NACE MR0175 / ISO 15156-3, 43 HRC maximum |
| Ultrasonic testing | ASTM A388, EN 10228-3, SEP 1921 |
| Certification | EN 10204 3.1 (mill) or 3.2 (third party: BV, SGS, TUV, DNV, ABS, LR) |
Inconel is a registered trademark of Special Metals Corporation. Trade names are listed here for identification only. Material supplied by Jiangyin Jiangnan Metal is certified to the UNS N07725 chemistry and to the customer specification.
Chemistry
Chemical composition of UNS N07725
| Element | Symbol | Weight % |
|---|---|---|
| Nickel | Ni | 55.0 to 59.0 |
| Chromium | Cr | 19.0 to 22.5 |
| Molybdenum | Mo | 7.0 to 9.5 |
| Niobium | Nb | 2.75 to 4.0 |
| Titanium | Ti | 1.0 to 1.7 |
| Aluminium | Al | 0.35 max |
| Manganese | Mn | 0.35 max |
| Silicon | Si | 0.20 max |
| Carbon | C | 0.03 max |
| Phosphorus | P | 0.015 max |
| Sulphur | S | 0.010 max |
| Iron | Fe | Balance |
The melting route for our N07725 forging stock is VIM plus ESR, or VIM plus ESR plus VAR where the end use calls for a higher cleanliness level. Double and triple melting keeps sulphur and phosphorus low and gives the segregation control needed for thick sour service sections.
Properties
Mechanical properties
Minimum specified properties, solution annealed and aged
| Property | Metric | Imperial |
|---|---|---|
| Tensile strength | 1035 MPa min | 150 ksi min |
| Yield strength, 0.2% offset | 827 MPa min | 120 ksi min |
| Elongation in 4D | 20 % min | 20 % min |
| Hardness, sour service | 43 HRC max | 43 HRC max |
The 43 HRC limit is the NACE MR0175 / ISO 15156-3 supply hardness ceiling for N07725 in sour service. The ageing cycle is set to keep the forging inside that limit while still meeting the strength minima.
Typical properties of age-hardened bar
| Condition | 0.2% YS | UTS | Elong. | Hardness | Charpy V |
|---|---|---|---|---|---|
| Annealed | 427 MPa | 855 MPa | 57 % | 5 HRC | n/a |
| Annealed and aged | 903 to 917 MPa | 1241 MPa | 30 to 31 % | 36 HRC | 92 to 132 J |
Alloy 725 holds its strength well as temperature rises. Average high temperature data for annealed and aged rod give a 0.2% yield strength of about 782 MPa at 315 °C and 778 MPa at 538 °C, with elongation above 29% across that range.
Properties
Physical properties
| Density | 8.31 g/cm³ (0.300 lb/in³) |
|---|---|
| Melting range | 1271 to 1343 °C (2320 to 2449 °F) |
| Young's modulus at 20 °C | 204 GPa (29.6 x 10³ ksi) |
| Shear modulus at 20 °C | 78 GPa |
| Poisson's ratio | 0.31 |
| Mean expansion 20 to 500 °C | 14.1 µm/m·°C |
| Electrical resistivity at 20 °C | 1.144 µΩ·m |
| Magnetic permeability at 15.9 kA/m | less than 1.001 |
Process
Heat treatment of N07725 forgings
N07725 is strengthened by gamma double prime precipitation during ageing, so the forging is solution annealed first and then double aged. The standard cycle we use for sour service work is set out below.
| Step | Parameters |
|---|---|
| Solution anneal | 1040 °C (1900 °F), air cool |
| First age | 732 °C (1350 °F), 8 h |
| Furnace cool | 56 °C/h (100 °F/h) to 620 °C |
| Second age | 620 °C (1150 °F), 8 h, air cool |
Air cooling after the solution anneal is preferred to water quenching. Where a component is welded, the best results are obtained by annealing before welding and applying a full solution anneal plus age after welding. Direct ageing of as-welded material gives low impact strength. GTAW and GMAW are the preferred welding processes with 725NDUR type filler metal. Submerged arc and shielded metal arc welding are not recommended.
Works practice
Open-die forging practice for alloy 725
Alloy 725 resists deformation more than most materials during hot working, so it needs adequate press capacity together with close control of temperature and reduction. The sequence we follow is set out below.
- Step 1VIM plus ESR billet, certified heat
- Step 2Heat to 899 to 1121 °C, short soak
- Step 3Open-die forge, 20% minimum final reduction
- Step 4Finish light passes at 899 to 954 °C
- Step 5Air cool, then solution anneal and double age
- Step 6Machine, UT, tensile, hardness, 3.1 certificate
- Hot working range is 899 to 1121 °C. The workpiece is reheated whenever any portion falls below 899 °C.
- Reductions are kept uniform to avoid a duplex grain structure. Final reduction is 20% minimum for open-die work and 10% minimum for closed-die work.
- The last operation is worked with gradually falling temperature and finished with light reduction in the 899 to 954 °C range. This is required to ensure notch ductility after annealing and ageing.
- Parts are air cooled from the forging temperature rather than water quenched.
- Tools and dies are preheated to 260 °C. Any rupture appearing on the surface of the workpiece is removed at once.
Grain size is reported on the certificate. For heavy sour service sections the target ASTM grain size is agreed with the end user before the first heat, because it affects both the ultrasonic acceptance level and the low temperature impact values.
Capability
UNS N07725 forged products and sizes
We forge N07725 to drawing in the following forms.
- Seamless rolled rings
- Forged flanges
- Forged round bars
- Discs and blanks
- Hollow forged tubes
- Sleeves and bushings
- Shafts and spindles
- Stepped spindles
- Tube sheets, valve bodies, stems, seat rings
| Form | Size range | Single piece weight |
|---|---|---|
| Seamless rolled rings | OD 200 to 3000 mm, height to 1000 mm | 20 to 8000 kg |
| Round bars | Dia. 60 to 800 mm | 10 to 6000 kg |
| Discs and blanks | Dia. 100 to 2500 mm | 20 to 8000 kg |
| Shafts and spindles | Dia. 80 to 900 mm, length to 6000 mm | 50 to 10000 kg |
| Sleeves and bushings | OD 100 to 1500 mm | 10 to 4000 kg |
Delivery condition can be as forged, rough machined, or finish machined to drawing. The standard supply condition is solution annealed and double aged, unless the order calls for annealed material for later forming.
Quality
Testing and certification
| Test | Standard |
|---|---|
| Chemical analysis | Product and heat analysis, spectrographic plus combustion for C and S |
| Tensile, room temperature | ASTM E8 / ISO 6892-1 |
| Hardness | ASTM E18, 43 HRC max for sour service |
| Charpy V-notch impact | ASTM E23, test temperature to order |
| Ultrasonic testing | ASTM A388, EN 10228-3, SEP 1921, 100% volumetric |
| Liquid penetrant | ASTM E165 / EN 10228-2 |
| Grain size | ASTM E112 |
| Certificate | EN 10204 3.1, or 3.2 witnessed by BV, SGS, TUV, DNV, ABS or LR |
Every forging is traceable to its heat number. The heat number appears on the certificate together with the melting route, the full heat treatment record with furnace charts, and the location and orientation of the test bar.
Applications
Applications for UNS N07725 forgings
| Industry | Components |
|---|---|
| Sour oil and gas, downhole | Hangers, landing nipples, side pocket mandrels, polished bore receptacles, packers, completion tools |
| Subsea and wellhead | Christmas tree bodies, connectors, hubs, tubing hangers, valve blocks and seat rings |
| Valves and pumps | Valve stems, gate and ball valve components, pump shafts, plungers, chemical pump sleeves |
| Pressure equipment | Forged flanges, tube sheets, nozzles, shell rings for heat exchangers and air receivers |
| Marine and seawater | High strength fasteners, studs and shafting resisting pitting and crevice attack in sea water |
| Power and rotating equipment | Turbine and compressor shafts, gears, spindles, gearbox components |
| Chemical process | Reactor internals, crystalliser parts, agitator shafts, mixing equipment |
In published C-ring testing, alloy 725 showed no cracking in 25% sodium chloride with 0.5% acetic acid and 1 g/l sulphur under 825 kPa hydrogen sulphide, at yield level stress up to about 232 °C. In a 30 day flowing seawater test it showed no crevice corrosion initiation, while annealed alloy 625 was attacked. For these reasons alloy 725 is used in deep sour wells in place of cold worked alloy 625 and alloy 718.
Grade selection
UNS N07725 compared with alloy 718, 625 and 925
| Alloy | UNS | Cr / Mo | Strengthening | Main advantage |
|---|---|---|---|---|
| Alloy 725 | N07725 | 21 / 8 | Gamma double prime | Highest corrosion resistance among the age hardened grades, sour service to 43 HRC without cold work |
| Alloy 718 | N07718 | 19 / 3 | Gamma double prime | Lower cost and higher temperature capability, but much lower molybdenum, so it cracks sooner in severe sour environments |
| Alloy 625 | N06625 | 21 / 9 | Solid solution | Similar corrosion resistance at about half the strength unless cold worked, and cold work reduces sour service margin |
| Alloy 925 | N09925 | 21 / 3 | Gamma prime | Lower cost Ni-Fe base for milder sour duty, with less pitting resistance than 725 |
| Alloy 716 | N07716 | 20 / 8 | Gamma double prime | Close to 725 and covered by the same ASTM B805 family, so the two are often cross quoted |
Alloy 725 is normally specified when the service environment is too severe for alloy 718 and the load case is too high for annealed alloy 625. If the grade has not yet been fixed, send us the service conditions and we will quote the alternatives.
Enquiry
How to order UNS N07725 forgings
Send a drawing or the finished dimensions to sales@steelforgepieces.com. Please include the following so that the enquiry can be priced without further questions.
- Drawing or rough dimensions, with the machining allowance you want us to leave
- Quantity and required delivery date
- Delivery condition: as forged, rough machined or finish machined
- Heat treatment condition: annealed, or solution annealed and double aged
- Acceptance standard and NDT level, and whether sour service applies
- Certificate type: EN 10204 3.1, or 3.2 with the third party you nominate
Questions
Frequently asked questions
What is UNS N07725?
UNS N07725 is an age-hardenable nickel-chromium-molybdenum-niobium alloy, nominally 57% Ni, 21% Cr, 8% Mo and 3.4% Nb. It has essentially the corrosion resistance of alloy 625 with about twice the strength of alloy 625 in the annealed condition, and it is approved under NACE MR0175 for sour gas wells.
Is UNS N07725 the same as Inconel 725?
Yes. Inconel 725 is the Special Metals trade name for the alloy whose UNS number is N07725. The same material is sold as Alloy 725, Nickelvac 725 and Nicrofer 5621, and carries Werkstoff number 2.4667. All of these refer to the same chemistry.
What is the difference between alloy 725 and alloy 718?
Both are strengthened by gamma double prime ageing. Alloy 725 carries about 8% molybdenum against roughly 3% in alloy 718, along with higher chromium and much lower aluminium. This gives alloy 725 better resistance to pitting, crevice corrosion and sulphide stress cracking. Alloy 718 remains the cheaper choice for high temperature duty in environments that are not sour.
Why choose alloy 725 instead of cold worked alloy 625?
Alloy 625 reaches high strength only through cold work, which cannot be applied uniformly to heavy or non-uniform forged sections and which reduces the sour service margin. In published C-ring testing, cold worked alloy 625 at 1103 MPa yield strength cracked, while age-hardened alloy 725 at a similar strength level did not. Age hardening also keeps ductility and toughness high.
What heat treatment is applied to N07725 forgings?
Solution anneal at 1040 °C followed by air cooling, then double ageing at 732 °C for 8 hours, furnace cool at 56 °C per hour to 620 °C, hold 8 hours and air cool. This is the recommended cycle for sour gas applications and is our default supply condition unless the order states otherwise.
Is UNS N07725 approved for sour service?
Yes. N07725 is listed under NACE MR0175 / ISO 15156-3 for sour oil and gas service, with a maximum supply hardness of 43 HRC. The ageing cycle is set to keep the forging inside that limit while still meeting the 1035 MPa tensile and 827 MPa yield minima.
At what temperature is alloy 725 forged?
Hot working is carried out between 899 °C and 1121 °C. The final passes are taken as light reductions in the 899 to 954 °C range, and the piece is reheated whenever any part drops below 899 °C. Final reduction is 20% minimum for open-die work to avoid a duplex grain structure, and parts are air cooled from the forging temperature rather than quenched.
What sizes of N07725 forgings can Jiangyin Jiangnan Metal supply?
We forge rolled rings up to about 3000 mm outside diameter, bars from 60 to 800 mm diameter, shafts up to 6000 mm long, and single pieces up to about 10 tonnes, all to customer drawing. Send the drawing and we will confirm the exact capability for your part.
What certification comes with the forgings?
EN 10204 3.1 as standard, covering chemistry, mechanical results, heat treatment records and heat traceability. EN 10204 3.2 certificates witnessed by BV, SGS, TUV, DNV, ABS or Lloyd's Register are available on request. Ultrasonic testing is carried out to ASTM A388, EN 10228-3 or SEP 1921.
Can you forge to my drawing, and what is the minimum order?
Yes. All of our N07725 work is forged to customer drawing rather than sold from stock, and single piece trial orders are accepted for qualification work. Lead time depends on billet availability and section size, and a firm date is confirmed with every quotation.
How is alloy 725 welded?
GTAW and GMAW with 725NDUR type filler metal are the preferred processes. Submerged arc and shielded metal arc welding are not recommended. The best results come from annealing the material before welding and giving it a full solution anneal plus age afterwards. Ageing as-welded material without a prior anneal gives low impact values.
Supplier
About the manufacturer
Jiangyin Jiangnan Metal Co., Ltd. is an open-die forging factory in Jiangyin, Jiangsu Province, China, within the Yangtze River delta forging area and close to the port of Shanghai. We forge carbon steel, alloy steel, tool steel, stainless steel and nickel alloys to customer drawing, including seamless rolled rings, flanges, bars, discs, sleeves, shafts and tube sheets, and supply them worldwide with EN 10204 certification.
- Company
- Jiangyin Jiangnan Metal Co., Ltd., open-die forging factory
- Address
- No.1 Chengxiqiao Road, Zhouzhuang Town, Jiangyin City, Jiangsu Province, China
- Phone
- 0086-189-2135-9659
- sales@steelforgepieces.com
- Website
- www.steelforgepieces.com
- Materials
- Nickel alloys, stainless steel, alloy steel, tool steel, carbon steel
- Languages
- English, Chinese
Document information
- Document
- UNS N07725 forgings, technical and supply data sheet
- Issued by
- Engineering department, Jiangyin Jiangnan Metal Co., Ltd.
- Revision
- Reference
- https://www.steelforgepieces.com/Nickel-Alloy/UNS-N07725.html
Sources used for the published alloy data:
- Special Metals Corporation, technical bulletin for alloy 725, publication SMC-066
- ASTM B805, precipitation hardening corrosion resistant nickel alloy bar and wire for downhole oil and gas applications
- NACE MR0175 / ISO 15156-3, materials for use in hydrogen sulphide containing environments
- ASME Code Case 2217
Size capability and works practice describe production at Jiangyin Jiangnan Metal Co., Ltd. Data is given for guidance and does not form a warranty. Enquiries and corrections to sales@steelforgepieces.com or 0086-189-2135-9659.
All nickel alloy grades we forge
- Alloy 59
- Alloy 602
- Hastelloy B
- Hastelloy B-2
- Hastelloy B-3
- Hastelloy B-4
- Hastelloy C-22
- Hastelloy C-276
- Hastelloy C-4
- Hastelloy C-2000
- Hastelloy G-3
- Haynes 25
- Haynes 188
- Haynes 230
- Incoloy 800
- Incoloy 800H
- Incoloy 800HT
- Incoloy 825
- Incoloy 890
- Incoloy 901
- Incoloy 925
- Incoloy 926
- Incoloy 945
- Inconel 600
- Inconel 601
- Inconel 617
- Inconel 625
- Inconel 690
- Inconel 693
- Inconel 706
- Inconel 718
- Inconel 725
- Inconel X-750
- Monel 400
- Monel K-500
- Monel R-405
- MP35N
- MP159
- Multimet N155
- NI-SPAN-C Alloy 902
- Nimonic 75
- Nimonic 80A
- Nimonic 81
- Nimonic 86
- Nimonic 90
- Nimonic 105
- Nimonic 115
- Nimonic 263
- Nimonic 901
- Rene 41
- Udimet 500
- Udimet 520
- Udimet 720
- UNS N07022
- UNS N07208
- UNS N07252
- UNS N07725
- Waspaloy